Reactions of tin tetrachloride with diethyl glutarate. Crystal structures of [Sn2Cl8{mu-C3H6(CO(2)Et)(2)}(2)]center dot 2CH(2)Cl(2) and cis-[SnCl4(H2O)(2)]center dot C3H6(CO(2)Et)(2)

被引：3

作者：

Sobota, P

Szafert, S

Glowiak, T

机构：

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 1996年 / 04期

关键词：

D O I：

10.1039/dt9960000439

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dimeric compound [Sn2Cl8{mu-C3H6(CO(2)Et)(2)}(2)]. 2CH(2)Cl(2) 1 has been prepared by direct reaction of SnCl4 with diethyl glutarate in CH2Cl2 and its crystal structure has been determined. Each tin atom is octahedrally co-ordinated by four chlorine atoms and two mutually cis carbonyl oxygen atoms of two bridging diethyl glutarate molecules. During the crystallization of 1 the compound cis-[SnCl4(H2O)(2)]. C3H6(CO(2)Et)(2) 2 was formed under the influence of moisture. Its crystal structure revealed a monomeric complex of Sn-IV in which each tin atom is surrounded octahedrally by four chlorine atoms and two water oxygen atoms. A non-co-ordinated ester molecule is hydrogen bonded through carbonyl oxygen atoms to one water molecule.

引用

页码：439 / 442

页数：4

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