Crystal structures of the isomorphous prototypic oxo-centered trinuclear complexes [Cr3O(OOCCH3)(6)(H2O)(3)]Cl center dot 6H(2)O and [Fe3O(OOCCH3)(6)(H2O)(3)]Cl center dot 6H(2)O

被引：56
|
作者：
Anson, CE [1 ]
Bourke, JP [1 ]
Cannon, RD [1 ]
Jayasooriya, UA [1 ]
Molinier, M [1 ]
Powell, AK [1 ]
机构：
[1] UNIV E ANGLIA, SCH CHEM SCI, NORWICH NR4 7TJ, NORFOLK, ENGLAND
来源：
INORGANIC CHEMISTRY | 1997年 / 36卷 / 06期
关键词：
D O I：
10.1021/ic960960f
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The two compounds [Cr3O(OOCCH3)(6)(H2O)(3)]Cl . 6H(2)O and [Fe3O(OOCCH3)(6)(H2O)(3)]Cl . 6H(2)O are the prototypes of the general class of trinuclear ''basis carboxylates''. New single-crystal X-ray structure determinations show that the two compounds are strictly isomorphous, with little disorder, and make it possible to quantify the extents of distortion of the molecules from idealized trigonal geometry.
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收藏
页码：1265 / +
页数：1
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