Ruthenium olefin metathesis catalysts for the 2 ethenolysis of renewable feedstocks

被引：101
|
作者：
Schrodi, Yann
Ung, Thay [1 ]
Vargas, Angel
Mkrtumyan, Garik [1 ]
Lee, Choon Woo [1 ]
Champagne, Timothy M. [1 ]
Pederson, Richard L. [1 ]
Hong, Soon Hyeok [1 ]
机构：
[1] Materia Inc, Pasadena, CA 91107 USA
来源：
CLEAN-SOIL AIR WATER | 2008年 / 36卷 / 08期
关键词：
ethenolysis; Grubbs catalyst; olefin metathesis; renewable feedstock; vegetable oil;
D O I：
10.1002/clen.200800088
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Ruthenium olefin metathesis catalysts have been evaluated for the ethenolysis of methyl oleate, a natural seed oil derivative, to produce useful terminal olefins. Several N-heterocyclic carbene-based ruthenium catalysts demonstrate good activity and selectivity for the formation of terminal olefins. In particular, catalysts (10) and (21) achieved higher TONs (> 20 000).
引用
收藏
页码：669 / 673
页数：5
相关论文
共 50 条
  • [41] Allenyl esters as quenching agents for ruthenium olefin metathesis catalysts
    Roy, Animesh
    Silvestri, Maximilian A.
    Hall, Robert A.
    Lepore, Salvatore D.
    [J]. TETRAHEDRON LETTERS, 2017, 58 (01) : 106 - 108
  • [42] Oxygen-chelated indenylidene ruthenium catalysts for olefin metathesis
    Xie, Yu
    Yuan, Ye
    Mousavi, Bibimaryam
    Cai, Yuan
    Kai, Cheng
    Lu, Yin
    Yusubov, Mehman
    Verpoort, Francis
    [J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2015, 29 (09) : 573 - 579
  • [43] Phosphites as ligands in ruthenium-benzylidene catalysts for olefin metathesis
    Schmid, Thibault E.
    Bantreil, Xavier
    Citadelle, Cecilia A.
    Slawin, Alexandra M. Z.
    Cazin, Catherine S. J.
    [J]. CHEMICAL COMMUNICATIONS, 2011, 47 (25) : 7060 - 7062
  • [44] Ruthenium Olefin Metathesis Catalysts Featuring a Labile Carbodicarbene Ligand
    Liberman-Martin, Allegra L.
    Grubbs, Robert H.
    [J]. ORGANOMETALLICS, 2017, 36 (21) : 4091 - 4094
  • [45] Catalysts for new tasks: Preparation and applications of tunable ruthenium catalysts for olefin metathesis
    Grela, Karol
    Michrowska, Anna
    Bieniek, Michal
    [J]. CHEMICAL RECORD, 2006, 6 (03): : 144 - 156
  • [46] Integrating the Schrock and Grubbs Catalysts: Ruthenium-Binaphtholate Catalysts for Olefin Metathesis
    Blacquiere, Johanna M.
    McDonald, Robert
    Fogg, Deryn E.
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2010, 49 (22) : 3807 - 3810
  • [47] Comparison of the kinetics of acyclic diene metathesis promoted by Grubbs ruthenium olefin metathesis catalysts
    Lehman, SE
    Wagener, KB
    [J]. MACROMOLECULES, 2002, 35 (01) : 48 - 53
  • [48] Synthesis and Evaluation of Ruthenium 2-Alkyl-6-mercaptophenolate Catalysts for Olefin Metathesis
    Wang, Tao
    Yu, Xiaobo
    Zhang, Huiqing
    Wu, Shutao
    Guo, Weijie
    Wang, Jianhui
    [J]. APPLIED ORGANOMETALLIC CHEMISTRY, 2019, 33 (07)
  • [49] σ/π Plasticity of NHCs on the Ruthenium-Phosphine and Ruthenium=Ylidene Bonds in Olefin Metathesis Catalysts
    Azofra, Luis Miguel
    Vummaleti, Sai V. C.
    Zhang, Ziyun
    Poater, Albert
    Cavallo, Luigi
    [J]. ORGANOMETALLICS, 2020, 39 (22) : 3972 - 3982
  • [50] Ruthenium nitronate complexes as tunable catalysts for olefin metathesis and other transformations
    Wdowik, Tomasz
    Samojlowicz, Cezary
    Jawiczuk, Magdalena
    Malinska, Maura
    Wozniak, Krzysztof
    Grela, Karol
    [J]. CHEMICAL COMMUNICATIONS, 2013, 49 (07) : 674 - 676
12345