Ruthenium olefin metathesis catalysts for the 2 ethenolysis of renewable feedstocks

被引：101
|
作者：
Schrodi, Yann
Ung, Thay [1 ]
Vargas, Angel
Mkrtumyan, Garik [1 ]
Lee, Choon Woo [1 ]
Champagne, Timothy M. [1 ]
Pederson, Richard L. [1 ]
Hong, Soon Hyeok [1 ]
机构：
[1] Materia Inc, Pasadena, CA 91107 USA
来源：
CLEAN-SOIL AIR WATER | 2008年 / 36卷 / 08期
关键词：
ethenolysis; Grubbs catalyst; olefin metathesis; renewable feedstock; vegetable oil;
D O I：
10.1002/clen.200800088
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
Ruthenium olefin metathesis catalysts have been evaluated for the ethenolysis of methyl oleate, a natural seed oil derivative, to produce useful terminal olefins. Several N-heterocyclic carbene-based ruthenium catalysts demonstrate good activity and selectivity for the formation of terminal olefins. In particular, catalysts (10) and (21) achieved higher TONs (> 20 000).
引用
收藏
页码：669 / 673
页数：5
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