Ruthenium olefin metathesis catalysts for the 2 ethenolysis of renewable feedstocks

被引：101

作者：

Schrodi, Yann

Ung, Thay ^{[1
]}

Vargas, Angel

Mkrtumyan, Garik ^{[1
]}

Lee, Choon Woo ^{[1
]}

Champagne, Timothy M. ^{[1
]}

Pederson, Richard L. ^{[1
]}

Hong, Soon Hyeok ^{[1
]}

机构：

[1] Materia Inc, Pasadena, CA 91107 USA

来源：

CLEAN-SOIL AIR WATER | 2008年 / 36卷 / 08期

关键词：

ethenolysis; Grubbs catalyst; olefin metathesis; renewable feedstock; vegetable oil;

D O I：

10.1002/clen.200800088

中图分类号：

X [环境科学、安全科学];

学科分类号：

08 ; 0830 ;

摘要：

Ruthenium olefin metathesis catalysts have been evaluated for the ethenolysis of methyl oleate, a natural seed oil derivative, to produce useful terminal olefins. Several N-heterocyclic carbene-based ruthenium catalysts demonstrate good activity and selectivity for the formation of terminal olefins. In particular, catalysts (10) and (21) achieved higher TONs (> 20 000).

引用

页码：669 / 673

页数：5

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