Synthesis and X-ray crystal structure of a novel zinc ''ate complex'', [Li(TMEDA)]Zn-2(CH(2)SiMe(2)SiMe(2)CH(2))(2)

被引：12
|
作者：
Wyrwa, R
Frohlich, HO
Gorls, H
机构：
[1] UNIV JENA,INST ANORGAN & ANALYT CHEM,D-07743 JENA,GERMANY
[2] UNIV JENA,MAX PLANCK GESELL,ARBEITSGRP CO2 CHEM,D-07743 JENA,GERMANY
来源：
ORGANOMETALLICS | 1996年 / 15卷 / 12期
关键词：
D O I：
10.1021/om950978i
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[Li(TMEDA)]Zn-2(CH(2)SiMe(2)SiMe(2)CH(2))(2) (6) (TMEDA = (CH3)(2)NCH2CH2N(CH3)(2)) was obtained in 70% yield by a one-pot reaction of ClCH(2)SiMe(2)SiMe(2)CH(2)Cl, ZnCl2, and lithium sodium alloy in diethyl ether. DTA investigations of the complex showed that thermal decomposition takes place at 148 degrees C; the molecular structure of 6 has been established by X-ray structure analysis.
引用
收藏
页码：2833 / 2835
页数：3
相关论文
共 50 条
12345