Synthesis and X-ray crystal structure of a novel zinc ''ate complex'', [Li(TMEDA)]Zn-2(CH(2)SiMe(2)SiMe(2)CH(2))(2)

被引：12

作者：

Wyrwa, R

Frohlich, HO

Gorls, H

机构：

[1] UNIV JENA,INST ANORGAN & ANALYT CHEM,D-07743 JENA,GERMANY

[2] UNIV JENA,MAX PLANCK GESELL,ARBEITSGRP CO2 CHEM,D-07743 JENA,GERMANY

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 12期

关键词：

D O I：

10.1021/om950978i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Li(TMEDA)]Zn-2(CH(2)SiMe(2)SiMe(2)CH(2))(2) (6) (TMEDA = (CH3)(2)NCH2CH2N(CH3)(2)) was obtained in 70% yield by a one-pot reaction of ClCH(2)SiMe(2)SiMe(2)CH(2)Cl, ZnCl2, and lithium sodium alloy in diethyl ether. DTA investigations of the complex showed that thermal decomposition takes place at 148 degrees C; the molecular structure of 6 has been established by X-ray structure analysis.

引用

页码：2833 / 2835

页数：3

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