Synthesis and X-ray crystal structure of a novel zinc ''ate complex'', [Li(TMEDA)]Zn-2(CH(2)SiMe(2)SiMe(2)CH(2))(2)

被引：12
|
作者：
Wyrwa, R
Frohlich, HO
Gorls, H
机构：
[1] UNIV JENA,INST ANORGAN & ANALYT CHEM,D-07743 JENA,GERMANY
[2] UNIV JENA,MAX PLANCK GESELL,ARBEITSGRP CO2 CHEM,D-07743 JENA,GERMANY
来源：
ORGANOMETALLICS | 1996年 / 15卷 / 12期
关键词：
D O I：
10.1021/om950978i
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
[Li(TMEDA)]Zn-2(CH(2)SiMe(2)SiMe(2)CH(2))(2) (6) (TMEDA = (CH3)(2)NCH2CH2N(CH3)(2)) was obtained in 70% yield by a one-pot reaction of ClCH(2)SiMe(2)SiMe(2)CH(2)Cl, ZnCl2, and lithium sodium alloy in diethyl ether. DTA investigations of the complex showed that thermal decomposition takes place at 148 degrees C; the molecular structure of 6 has been established by X-ray structure analysis.
引用
收藏
页码：2833 / 2835
页数：3
相关论文
共 50 条
  • [31] Isolation and X-ray crystal structures of {Li-2[mu(2)-As(SiMe(3))(2)][mu(3)-As(SiMe(3))(2)](THF)}(2) and [(Me(3)Si)(2)AsLi(THF)(2)](2)
    Jones, LJ
    McPhail, AT
    Wells, RL
    JOURNAL OF COORDINATION CHEMISTRY, 1995, 34 (02) : 119 - 127
  • [32] Synthesis and characterization of arsacycloalkanes and their palladium and platinum complexes, and X-ray structure of [PdCl2(PhAsCH2CH2CH2CH2CH2)2]
    Garje, SS
    Jain, VK
    Varghese, B
    APPLIED ORGANOMETALLIC CHEMISTRY, 1999, 13 (01) : 47 - 51
  • [33] Synthesis and molecular structure of [Mg(CH2SiMe3)(μ3-OCH2SiMe3)]4
    Moreno, Carlos Alonso
    Hughes, David L.
    Bochmann, Manfred
    POLYHEDRON, 2007, 26 (12) : 2523 - 2526
  • [34] Os(N)(CH2SiMe3)2(SCH2CH2S).
    Zhang, Naijie
    Wilson, Scott R.
    Shapley, Patricia A.
    1988, 7 (05) : 1126 - 1131
  • [35] Double silyl migration converting ORe[N(SiMe2CH2PCy2)2] to NRe[O(SiMe2CH2PCy2)2] substructures
    Ozerov, OV
    Gerard, HF
    Watson, LA
    Huffman, JC
    Caulton, KG
    INORGANIC CHEMISTRY, 2002, 41 (21) : 5615 - 5625
  • [36] The Bis Metallacyclic Anion [U(N{SiMe3}2)(CH2SiMe2N{SiMe3})2]-
    Benaud, Olivier
    Berthet, Jean-Claude
    Thuery, Pierre
    Ephritikhine, Michel
    INORGANIC CHEMISTRY, 2010, 49 (17) : 8117 - 8130
  • [37] SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF [LI2CU2(CH2SIME3)4(SME2)2]INFINITY - THE 1ST DETAILED STRUCTURAL CHARACTERIZATION OF A LITHIUM DIALKYLCUPRATE AGGREGATE
    OLMSTEAD, MM
    POWER, PP
    ORGANOMETALLICS, 1990, 9 (06) : 1720 - 1722
  • [38] X-RAY STRUCTURE OF A DERIVATIVE OF THE SIMPLEST METALLOCENE - CYCLOPENTADIENYLLITHIUM, [LI(ETA-C5H4(SIME3))(NME2(CH2)2NME2)] (IE LICP'(TMEDA))
    LAPPERT, MF
    SINGH, A
    ENGELHARDT, LM
    WHITE, AH
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1984, 262 (03) : 271 - 278
  • [39] STRUCTURE AND REACTIVITY OF STERICALLY HINDERED LITHIUM AMIDES AND THEIR DIETHYL ETHERATES - CRYSTAL AND MOLECULAR-STRUCTURES OF [LI(N(SIME3)2)(OET2)]2 AND [LI(NCME2CH2CH2CH2CME2)]4
    LAPPERT, MF
    SLADE, MJ
    SINGH, A
    ATWOOD, JL
    ROGERS, RD
    SHAKIR, R
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (02) : 302 - 304
  • [40] Synthesis and characterization of the five-coordinate scandium dialkyl complexes ScR(2)[N(SiMe(2)CH(2)PPr(2)(i))(2)] (R=Me, Et, CH(2)SiMe(3))
    Fryzuk, MD
    Giesbrecht, G
    Rettig, SJ
    ORGANOMETALLICS, 1996, 15 (15) : 3329 - 3336
12345