Synthesis and X-ray crystal structure of a novel zinc ''ate complex'', [Li(TMEDA)]Zn-2(CH(2)SiMe(2)SiMe(2)CH(2))(2)

被引：12

作者：

Wyrwa, R

Frohlich, HO

Gorls, H

机构：

[1] UNIV JENA,INST ANORGAN & ANALYT CHEM,D-07743 JENA,GERMANY

[2] UNIV JENA,MAX PLANCK GESELL,ARBEITSGRP CO2 CHEM,D-07743 JENA,GERMANY

来源：

ORGANOMETALLICS | 1996年 / 15卷 / 12期

关键词：

D O I：

10.1021/om950978i

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

[Li(TMEDA)]Zn-2(CH(2)SiMe(2)SiMe(2)CH(2))(2) (6) (TMEDA = (CH3)(2)NCH2CH2N(CH3)(2)) was obtained in 70% yield by a one-pot reaction of ClCH(2)SiMe(2)SiMe(2)CH(2)Cl, ZnCl2, and lithium sodium alloy in diethyl ether. DTA investigations of the complex showed that thermal decomposition takes place at 148 degrees C; the molecular structure of 6 has been established by X-ray structure analysis.

引用

页码：2833 / 2835

页数：3

共 50 条

[1] SYNTHESIS OF [LI(CH2SIME3) (PMDETA)] AND THE CRYSTALLINE MONOMERIC BULKY ALKYL-LITHIUM COMPLEXES [LIR(TMEDA)] AND [LIR(PMDETA)] [R = CH(SIME3)2] - X-RAY CRYSTAL-STRUCTURE OF [LI(CH(SIME3)2)(PMDETA)] (TMEDA = ME2NCH2CH2NME2, PMDETA = ME2N[CH2]2N(ME)[CH2]2NME2)
LAPPERT, MF
ENGELHARDT, LM
RASTON, CL
WHITE, AH
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1982, (22) : 1323 - 1324
[2] Novel chelated diorganolithate ion [CH(2)SiMe(2)C(SiMe(3))(2)LiC(SiMe(3))(2)SiMe(2)CH(2)](-) and highly crowded chelated organomercury compound [CH(2)SiMe(2)C(SiMe(3))(2)HgC(SiMe(3))(2)SiMe(2)CH(2)]
Eaborn, C
Lu, ZR
Hitchcock, PB
Smith, JD
ORGANOMETALLICS, 1996, 15 (06) : 1651 - 1655
[3] Synthesis and characterization of substituted benzyl zinc derivatives molecular structures of (tmeda)Li-CH(GeMe3)Ph, (tmeda)Zn(CH2Ph)(2), (tmeda)Zn[CH(SiMe3)Ph](2), and (tmeda)Zn[CH(SiMe3)Ph]N(H)Si(SiMe3)(3)
Westerhausen, M
Wieneke, M
Rademacher, BB
Schwarz, W
CHEMISCHE BERICHTE-RECUEIL, 1997, 130 (10): : 1499 - 1505
[4] PHOSPHINE COMPLEXES OF YTTRIUM, LANTHANUM, AND LUTETIUM - SYNTHESIS, THERMOLYSIS, AND FLUXIONAL BEHAVIOR OF THE HYDROCARBYL DERIVATIVES MR'[N(SIME2CH2PME2)2]2 - X-RAY CRYSTAL-STRUCTURE OF Y[N(SIME2CHPME2)(SIME2CH2PME2)][N(SIME2CH2PME2)2]
FRYZUK, MD
HADDAD, TS
RETTIG, SJ
ORGANOMETALLICS, 1991, 10 (06) : 2026 - 2036
[5] Phosphine complexes of yttrium, lanthanum, and lutetium. Synthesis, thermolysis, and fluxional behavior of the hydrocarbyl derivatives MR prime [N(SiMe2CH2PMe2)2]. X-ray crystal structure of Y[N(SiMe2CHPMe2)(SiMe2CH2PMe2)] [N(SiMe2CH2PMe2)2]
Fryzuk, Michael D.
Haddad, T.S.
Rettig, Steven J.
Organometallics, 1991, 10 (06)
[6] SYNTHESIS OF [LI(TMEDA)]PT-2(CH(2)CME(2)CME(2)CH)(2))(2) - COMPARISON OF DECOMPOSITION TEMPERATURES OF ITS METALLACYCLOPENTANE COMPLEXES OF PT(II) AND NI(II) WITH AND WITHOUT BETA-HYDROGEN - CRYSTAL-STRUCTURE OF (COD)PTCH(2)SIME(2)SIME(2)CH2
WYRWA, R
FROHLICH, HO
GORLS, H
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 503 (01) : 135 - 141
[7] TITANIUM(IV) COMPLEXES INCORPORATING THE AMINODIAMIDE LIGAND [(SIME(3))N(CH2CH2N(SIME(3)))(2)](2-)(L) - THE X-RAY CRYSTAL-STRUCTURES OF [TIME(2)(L)] AND [TICL(CH(SIME(3))(2))(L)]
CLARK, HCS
CLOKE, GN
HITCHCOCK, PB
LOVE, JB
WAINWRIGHT, AP
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 501 (1-2) : 333 - 340
[8] ALKYL COMPLEXES OF COBALT(II) - X-RAY CRYSTAL-STRUCTURES OF (ME2NCH2CH2NME2)CO CH2SIME3, CH2CME3, [(ME2NCH2CH2NME2)LI]2[CO(CH2SIME3)4] 2 AND (ME2NCH2CH2NME2)CO[(ME2NCH2CH2NME2)2LI] [COCL(CH[SIME3]2)2]2
HAYMOTHERWELL, RS
WILKINSON, G
HUSSAIN, B
HURSTHOUSE, MB
POLYHEDRON, 1990, 9 (07) : 931 - 937
[9] A novel organolead(II) species, the plumbacycloalkane derivative [CH2SiMe2C(SiMe3)2PbC(SiMe3)2SiMe2CH2]
Eaborn, C
Ganicz, T
Hitchcock, PB
Smith, JD
Sozerli, SE
ORGANOMETALLICS, 1997, 16 (26) : 5621 - 5622
[10] Phosphinoalkylsilyl complexes.: 12.: Stereochemistry of the tridentate bis(diphenylphosphinopropyl)silyl (biPSi) framework:: Complexation that introduces "face discrimination" at coordinatively unsaturated metal centers.: X-ray crystal and molecular structures of Pt[SiMe(CH2CH2CH2PPh2)2]Cl, IrH[SiMe(CH2CH2CH2PPh2)2]Cl, and RuH[SiMe(CH2CH2CH2PPh2)2](CO)2
Brost, RD
Bruce, GC
Joslin, FL
Stobart, SR
ORGANOMETALLICS, 1997, 16 (26) : 5669 - 5680

← 1 2 3 4 5 →