Crystal structure and Hirshfeld surface analysis of phenyl(5,7,8a-triphenyl-1,2,3,7,8,8a-hexahydroimidazo[1,2-a]pyridin-6-yl)methanone with an unknown solvent

被引:3
|
作者
Naghiyev, Farid N. [1 ]
Mammadova, Gunay Z. [1 ]
Mamedov, Ibrahim G. [1 ]
Huseynova, Afet T. [1 ]
Celikesir, Sevim Turktekin [2 ]
Akkurt, Mehmet [2 ]
Akobirshoeva, Anzurat A. [3 ]
机构
[1] Baku State Univ, Organ Chem Dept, Z Xalilov Str 23, AZ-1148 Baku, Azerbaijan
[2] Erciyes Univ, Fac Sci, Dept Phys, TR-38039 Kayseri, Turkey
[3] Acad Sci Republ Tadzhikistan, Kh Yu Yusuibekov Pamir Biol Inst, 1 Kholdorova St, Khorog 736002, Gbao, Tajikistan
关键词
crystal structure; cycloaddition products; hexahydroimidazo[1,2-a]pyridine ring; SQUEEZE;
D O I
10.1107/S2056989020009871
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C32H28N2O, the imidazolidine and pyridine rings of the central hexahydroimidazo[1,2-a]pyridine ring system adopt envelope and screw-boat conformations, respectively. The molecule exhibits two weak intramolecular pi-pi interactions between phenyl rings. In the crystal, molecules are linked via pairs of C-H center dot center dot center dot O hydrogen bonds, forming inversion dimers. The dimers are further linked by pairs of C-H center dot center dot center dot pi interactions, forming infinite chains along the c-axis direction. A Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H center dot center dot center dot H (73.4%), C center dot center dot center dot H/H center dot center dot center dot C (18.8%) and O center dot center dot center dot H/H center dot center dot center dot O (5.7%) contacts. The contribution of some disordered solvent to the scattering was removed using the SQUEEZE routine [Spek (2015). Acta Cryst. C71, 9-18] in PLATON. The solvent contribution was not included in the reported molecular weight and density.
引用
收藏
页码:1365 / +
页数:11
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