Crystal structure and Hirshfeld surface analysis of phenyl(5,7,8a-triphenyl-1,2,3,7,8,8a-hexahydroimidazo[1,2-a]pyridin-6-yl)methanone with an unknown solvent

被引：3

作者：

Naghiyev, Farid N. ^{[1
]}

Mammadova, Gunay Z. ^{[1
]}

Mamedov, Ibrahim G. ^{[1
]}

Huseynova, Afet T. ^{[1
]}

Celikesir, Sevim Turktekin ^{[2
]}

Akkurt, Mehmet ^{[2
]}

Akobirshoeva, Anzurat A. ^{[3
]}

机构：

[1] Baku State Univ, Organ Chem Dept, Z Xalilov Str 23, AZ-1148 Baku, Azerbaijan

[2] Erciyes Univ, Fac Sci, Dept Phys, TR-38039 Kayseri, Turkey

[3] Acad Sci Republ Tadzhikistan, Kh Yu Yusuibekov Pamir Biol Inst, 1 Kholdorova St, Khorog 736002, Gbao, Tajikistan

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2020年 / 76卷

关键词：

crystal structure; cycloaddition products; hexahydroimidazo[1,2-a]pyridine ring; SQUEEZE;

D O I：

10.1107/S2056989020009871

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, C32H28N2O, the imidazolidine and pyridine rings of the central hexahydroimidazo[1,2-a]pyridine ring system adopt envelope and screw-boat conformations, respectively. The molecule exhibits two weak intramolecular pi-pi interactions between phenyl rings. In the crystal, molecules are linked via pairs of C-H center dot center dot center dot O hydrogen bonds, forming inversion dimers. The dimers are further linked by pairs of C-H center dot center dot center dot pi interactions, forming infinite chains along the c-axis direction. A Hirshfeld surface analysis indicates that the most important contributions to the crystal packing are from H center dot center dot center dot H (73.4%), C center dot center dot center dot H/H center dot center dot center dot C (18.8%) and O center dot center dot center dot H/H center dot center dot center dot O (5.7%) contacts. The contribution of some disordered solvent to the scattering was removed using the SQUEEZE routine [Spek (2015). Acta Cryst. C71, 9-18] in PLATON. The solvent contribution was not included in the reported molecular weight and density.

引用

页码：1365 / +

页数：11

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