Synthesis and crystal structure of 2-propyl-5-phenyl-1,4-dioxo-1,2,3,4,5,6,7,8-octahydro-[1,4,2]diazaphosphorino[1,2-a][1,3,2]benzodiazaphosphorine 3-oxide

被引：2

作者：

Huang, JM ^{[1
]}

Chen, H

Chen, RY

机构：

[1] Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China

[2] Procter & Gamble Technol Beijing Co, Beijing, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2001年 / 31卷 / 9-10期

基金：

中国国家自然科学基金;

关键词：

crystal structure; 1,4,2]diazaphosphorino[1,2-a][1,3,2]benzodiazaphosphorine;

D O I：

10.1023/A:1015683720074

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The synthesis and structure characterization of 2-propyl-5-phenyl-1,4-dioxo-1,2,3,4,5, 6,7,8-octahydro-[1,4,2]diazaphosphorino[1,2-a][1,3,2]benzodiazaphosphorine 3-oxide are described. The title compound has been designed to incorporate proximate carbonyl and phosphoryl groups in a heterocycle fused to benzophosphadiamide heterocycle. Crystal data: C(1)9H(2)0N(3)O(3)P, Monoclinic, space group P2(1)/c, with a = 9.7585(9) Angstrom, b = 21.4319(19) Angstrom, c = 17.7900(16) Angstrom, beta = 100.823(2)degrees, Z = 8, V = 3654.5(6) Angstrom(3). The crystal structure shows that the proximate carbonyl and phosphoryl groups are not coplanar, and the [1,4,2]diazaphosphorino moiety prefers the boat conformation.

引用

页码：445 / 452

页数：8

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