Palladium-Catalyzed Desulfitative Arylation by C-O Bond Cleavage of Aryl Inflates with Sodium Arylsulfinates

被引：72

作者：

Zhou, Chao ^{[1
]}

Liu, Qingjiang ^{[1
]}

Li, Yaming ^{[1
]}

Zhang, Rong ^{[1
]}

Fu, Xinmei ^{[1
]}

Duan, Chunying ^{[1
]}

机构：

[1] Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 77卷 / 22期

基金：

中国国家自然科学基金;

关键词：

UNSYMMETRICAL DIARYL SULFONES; CROSS-COUPLING REACTIONS; II RECEPTOR ANTAGONISTS; DIRECT ESI-MS; GRIGNARD-REAGENTS; SULFINIC ACIDS; DISCOVERY; CHLORIDES; BIARYL; KETONES;

D O I：

10.1021/jo302005s

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient Pd-catalyzed desulfitative coupling reaction of sodium arylsulfinates as arylation reagents by C-O bond cleavage of aryl triflates was developed. With only 2 mol % of Pd(OAc)(2) as catalyst and XPhos as ligand, the reaction proceeded well for a range of substrates.

引用

页码：10468 / 10472

页数：5

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