Palladium-Catalyzed Desulfitative C?H Arylation of Heteroarenes with Sodium Sulfinates

被引：132
|
作者：
Liu, Bo [1 ,2 ]
Guo, Qiang [1 ,2 ]
Cheng, Yangyang [1 ,2 ]
Lan, Jingbo [1 ,2 ]
You, Jingsong [1 ,2 ]
机构：
[1] Sichuan Univ, Key Lab Green Chem & Technol, Minist Educ, Coll Chem,W China Med Sch, Chengdu 610064, Peoples R China
[2] Sichuan Univ, State Key Lab Biotherapy, W China Med Sch, Chengdu 610064, Peoples R China
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2011年 / 17卷 / 48期
关键词：
C?H activation; cross-coupling; heterocycles; palladium; sodium sulfinates; INTERMOLECULAR DIRECT ARYLATION; H ARYLATION; DIRECT FUNCTIONALIZATION; XANTHINE DERIVATIVES; COUPLING REACTIONS; ARYLBORONIC ACIDS; BOND FORMATION; PHOSPHINE-FREE; HIGHLY POTENT; ARYL SULFONES;
D O I：
10.1002/chem.201102644
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Desulfitative C-H arylation: Palladium-catalyzed desulfitative C-H arylation of heteroarenes with sodium sulfinates has been disclosed to construct aryl-heteroaryl bonds without the need for any extra ligands (see scheme). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：13415 / 13419
页数：5
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