Palladium-Catalyzed Desulfitative Arylation by C-O Bond Cleavage of Aryl Inflates with Sodium Arylsulfinates

被引：72
|
作者：
Zhou, Chao [1 ]
Liu, Qingjiang [1 ]
Li, Yaming [1 ]
Zhang, Rong [1 ]
Fu, Xinmei [1 ]
Duan, Chunying [1 ]
机构：
[1] Dalian Univ Technol, Sch Chem Engn, State Key Lab Fine Chem, Dalian 116024, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 77卷 / 22期
基金：
中国国家自然科学基金;
关键词：
UNSYMMETRICAL DIARYL SULFONES; CROSS-COUPLING REACTIONS; II RECEPTOR ANTAGONISTS; DIRECT ESI-MS; GRIGNARD-REAGENTS; SULFINIC ACIDS; DISCOVERY; CHLORIDES; BIARYL; KETONES;
D O I：
10.1021/jo302005s
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient Pd-catalyzed desulfitative coupling reaction of sodium arylsulfinates as arylation reagents by C-O bond cleavage of aryl triflates was developed. With only 2 mol % of Pd(OAc)(2) as catalyst and XPhos as ligand, the reaction proceeded well for a range of substrates.
引用
收藏
页码：10468 / 10472
页数：5
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