Ru, Rh, and Ir trinuclear mixed-valence oxygen-bridged carboxylate complexes

被引：3
|
作者：
Belyaev, AN [1 ]
Simanova, SA [1 ]
机构：
[1] State Tech Univ, St Petersburg State Technol Inst, St Petersburg 198013, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2004年 / 30卷 / 03期
关键词：
D O I：
10.1023/B:RUCO.0000022116.14783.b3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A model is suggested that can be used to explain the structure of amorphous (glassy) mixed-valence Z trinuclear mu(3)-oxocarboxylate complexes of ruthenium, rhodium, and iridium. In the framework of this model, individual metal-containing blocks that formally occur in different oxidized states are considered to be structurally and functionally integrated in a single supramolecular construction.
引用
收藏
页码：184 / 193
页数：10
相关论文
共 50 条
  • [1] Ru, Rh, and Ir Trinuclear Mixed-Valence Oxygen-Bridged Carboxylate Complexes
    A. N. Belyaev
    S. A. Simanova
    [J]. Russian Journal of Coordination Chemistry, 2004, 30 : 184 - 193
  • [2] TRINUCLEAR MIXED-VALENCE COMPLEXES OF COPPER
    DATTA, D
    CHAKRAVORTY, A
    [J]. INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1981, 20 (03): : 289 - 290
  • [3] Synthesis and spectral characterization of trinuclear, oxo-centered, carboxylate-bridged, mixed-valence iron complexes with Schiff bases
    Singh, Atresh Kumar
    Singh, Alok Kumar
    [J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2012, 96 : 986 - 991
  • [4] Resonance Raman investigation of mixed-valence dinuclear and trinuclear complexes of Ru, Os and Re
    Bignozzi, CA
    Argazzi, R
    Strouse, GF
    Schoonover, JR
    [J]. INORGANICA CHIMICA ACTA, 1998, 276 (1-2) : 380 - 384
  • [5] TRINUCLEAR MIXED-VALENCE COMPLEXES WITH THE LINEAR [RH3]4+ CORE
    CONNELLY, NG
    LOYNS, AC
    CIRIANO, MA
    FERNANDEZ, MJ
    ORO, LA
    VILLARROYA, BE
    [J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1989, (04): : 689 - 691
  • [6] Trinuclear, oxo-bridged, mixed-valence iron mercaptocarboxylates
    Pandey, AK
    Gupta, T
    Baranwal, BP
    [J]. TRANSITION METAL CHEMISTRY, 2004, 29 (04) : 370 - 375
  • [7] Trinuclear, Oxo-Bridged, Mixed-Valence Iron Mercaptocarboxylates
    Ashutosh K. Pandey
    Tarkeshwar Gupta
    Balram P. Baranwal
    [J]. Transition Metal Chemistry, 2004, 29 : 370 - 375
  • [8] Electron density distributions of redox active mixed valence carboxylate bridged trinuclear iron complexes
    Overgaard, J
    Larsen, FK
    Schiott, B
    Iversen, BB
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (36) : 11088 - 11099
  • [9] Mixed-valence states of Fe-57-atoms produced in trinuclear cobalt-iron and trinuclear iron carboxylate complexes
    Sato, T
    Ambe, F
    [J]. INTERNATIONAL CONFERENCE ON THE APPLICATIONS OF THE MOSSBAUER EFFECT - ICAME-95, 1996, 50 : 27 - 30
  • [10] Spectroscopic studies of oxo-centered, carboxylate-bridged, trinuclear mixed-valence iron (III, III, II) complexes with aromatic hydroxycarboxylic acids
    Singh, Atresh Kumar
    Singh, Alok Kumar
    [J]. SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2013, 112 : 422 - 428
12345