Ru, Rh, and Ir Trinuclear Mixed-Valence Oxygen-Bridged Carboxylate Complexes

被引：0
|
作者：
A. N. Belyaev
S. A. Simanova
机构：
[1] St. Petersburg State Technological Institute (Technical University),
来源：
Russian Journal of Coordination Chemistry | 2004年 / 30卷
关键词：
Physical Chemistry; Carboxylate; Ruthenium; Rhodium; Iridium;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A model is suggested that can be used to explain the structure of amorphous (glassy) mixed-valence trinuclear μ3-oxocarboxylate complexes of ruthenium, rhodium, and iridium. In the framework of this model, individual metal-containing blocks that formally occur in different oxidized states are considered to be structurally and functionally integrated in a single supramolecular construction.
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页码：184 / 193
页数：9
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