Ru, Rh, and Ir trinuclear mixed-valence oxygen-bridged carboxylate complexes

被引：3

作者：

Belyaev, AN ^{[1
]}

Simanova, SA ^{[1
]}

机构：

[1] State Tech Univ, St Petersburg State Technol Inst, St Petersburg 198013, Russia

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2004年 / 30卷 / 03期

关键词：

D O I：

10.1023/B:RUCO.0000022116.14783.b3

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A model is suggested that can be used to explain the structure of amorphous (glassy) mixed-valence Z trinuclear mu(3)-oxocarboxylate complexes of ruthenium, rhodium, and iridium. In the framework of this model, individual metal-containing blocks that formally occur in different oxidized states are considered to be structurally and functionally integrated in a single supramolecular construction.

引用

页码：184 / 193

页数：10

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