Ru, Rh, and Ir trinuclear mixed-valence oxygen-bridged carboxylate complexes

被引：3
|
作者：
Belyaev, AN [1 ]
Simanova, SA [1 ]
机构：
[1] State Tech Univ, St Petersburg State Technol Inst, St Petersburg 198013, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2004年 / 30卷 / 03期
关键词：
D O I：
10.1023/B:RUCO.0000022116.14783.b3
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A model is suggested that can be used to explain the structure of amorphous (glassy) mixed-valence Z trinuclear mu(3)-oxocarboxylate complexes of ruthenium, rhodium, and iridium. In the framework of this model, individual metal-containing blocks that formally occur in different oxidized states are considered to be structurally and functionally integrated in a single supramolecular construction.
引用
收藏
页码：184 / 193
页数：10
相关论文
共 50 条
  • [31] REDOX PROPERTIES OF OXO-BRIDGED DINUCLEAR AND TRINUCLEAR COMPLEXES OF HEAVY TRANSITION-ELEMENTS - STABILITY OF MIXED-VALENCE STATE
    SASAKI, Y
    [J]. JOURNAL OF MOLECULAR LIQUIDS, 1995, 65-6 : 253 - 260
  • [32] Synthesis and characterization of spin-delocalized carboxylate-bridged Cu(I)-Cu(II) mixed-valence complexes having only oxygen donor ligands
    LeCloux, DD
    Davydov, R
    Lippard, SJ
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (27) : 6810 - 6811
  • [33] Triply bridged dinuclear ruthenium complexes bearing alkylbis(2-pyridylmethyl)amine in the mixed-valence state of Ru(II)-Ru(III)
    Misawa-Suzuki, T.
    Matsuya, K.
    Watanabe, T.
    Nagao, H.
    [J]. DALTON TRANSACTIONS, 2018, 47 (45) : 16182 - 16189
  • [34] IR STUDY OF THE H-BOND COUPLED WITH THE MIXED-VALENCE STATE OF HALOGEN-BRIDGED METAL-COMPLEXES
    OKANIWA, K
    OKAMOTO, H
    MITANI, T
    TORIUMI, K
    YAMASHITA, M
    [J]. JOURNAL OF THE PHYSICAL SOCIETY OF JAPAN, 1991, 60 (03) : 997 - 1004
  • [35] Gas Adsorption of Mixed-Valence Trinuclear Oxothiomolybdenum Glycolates
    Deng, Lan
    Dong, Xing
    An, Dong-Li
    Weng, Wei-Zheng
    Zhou, Zhao-Hui
    [J]. INORGANIC CHEMISTRY, 2020, 59 (07) : 4874 - 4881
  • [36] OXIDATION OF STYRENE CATALYZED BY MU-OXOTRINUCLEAR MIXED-VALENCE AND MIXED METAL CARBOXYLATE COMPLEXES
    KANAI, H
    HAYASHI, H
    KOIKE, T
    OHSUGA, M
    MATSUMOTO, M
    [J]. JOURNAL OF CATALYSIS, 1992, 138 (02) : 611 - 616
  • [37] Femtosecond pump-probe spectroscopy of trinuclear transition metal mixed-valence complexes
    Watson, DF
    Tan, HS
    Schreiber, E
    Mordas, CJ
    Bocarsly, AB
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2004, 108 (16): : 3261 - 3267
  • [38] Redox interaction in mixed-valence trinuclear ring complexes by means of quantum chemical approach
    Chen, JY
    Aoki, K
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 1996, 402 (1-2): : 189 - 193
  • [39] Stable mixed-valence diphenylphosphanido bridged platinum(ii)-platinum(iv) complexes
    Fortuno, Consuelo
    Martin, Antonio
    Mastrorilli, Piero
    Latronico, Mario
    Petrelli, Valentina
    Todisco, Stefano
    [J]. DALTON TRANSACTIONS, 2020, 49 (15) : 4935 - 4955
  • [40] MIXED-VALENCE PYRAZINE-BRIDGED COMPLEXES OF RUTHENIUM CONTAINING SUBSTITUTED PHENANTHROLINES
    CLONINGER, KK
    CALLAHAN, RW
    [J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1980, 180 (AUG): : 343 - INOR
12345