Synthesis of Terpineol from α-Pinene Using Low-Price Acid Catalyst

被引：26
|
作者：
Prakoso, Tirto [1 ,2 ]
Hanley, Jonathan [1 ]
Soebianta, Mellisa Nathania [1 ]
Soerawidjaja, Tatang Hernas [1 ,2 ]
Indarto, Antonius [1 ,2 ]
机构：
[1] Inst Teknol Bandung, Chem Engn Dept, Labtek 10,Kampus ITB,Jalan Ganesha 10, Bandung 40132, Indonesia
[2] Inst Teknol Bandung, Bioenergy & Chemurgy Engn Dept, Kampus ITB Jatinangor, Kabupaten Sumedang 45363, Indonesia
来源：
CATALYSIS LETTERS | 2018年 / 148卷 / 02期
关键词：
alpha-Pinene; Terpineol; One-stage reaction; Hydration; Acid catalyst;
D O I：
10.1007/s10562-017-2267-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This study aims to produce terpineol from alpha-pinene by direct one-stage hydration reaction mechanism. The study was focused to investigate the influence of organic acids and mixture acid catalyst between organic acid and phosphoric acid. Based on the experimental results and depending on the acid strength and affinity of catalyst to the carbocation mechanism, p-toluensulfonic acid was shown to have a better result compared to acetic and formic acid. The presence of phosphoric acid could boost the performance of acetic acid in term of acidity strength that increased the conversion of the reaction. The highest yield of terpineol from alpha-pinene in this hydration reaction in this study was 53.5 wt% using mixed phosphoric and acetic acid. Graphical Abstract [GRAPHICS] .
引用
收藏
页码：725 / 731
页数：7
相关论文
共 50 条
  • [1] Synthesis of Terpineol from α-Pinene Using Low-Price Acid Catalyst
    Tirto Prakoso
    Jonathan Hanley
    Mellisa Nathania Soebianta
    Tatang Hernas Soerawidjaja
    Antonius Indarto
    [J]. Catalysis Letters, 2018, 148 : 725 - 731
  • [2] Synthesis of terpineol from α-pinene by homogeneous acid catalysis
    Román-Aguirre, M
    De la Torre-Sáenz, L
    Flores, WA
    Robau-Sánchez, A
    Elguézabal, AA
    [J]. CATALYSIS TODAY, 2005, 107-08 : 310 - 314
  • [3] Ionic liquid as green solvent for the synthesis of α-terpineol from α-pinene
    Aguilar-Elguezabal, A.
    De la Torre-Saenz, L.
    Roman-Aguirre, M.
    Alvarez-Contreras, L.
    [J]. SUSTAINABLE CHEMISTRY AND PHARMACY, 2020, 15
  • [4] Synthesis of Terpineol from Alpha-Pinene Catalyzed by α-Hydroxy Acids
    Meng, Zhong-Lei
    Wen, Ru-Si
    Huang, Xiao-Rui
    Qin, Rong-Xiu
    Hu, Yi-Ming
    Zhou, Yong-Hong
    [J]. MOLECULES, 2022, 27 (03):
  • [5] Enhanced α-Terpineol Yield from α-Pinene Hydration via Synergistic Catalysis Using Carbonaceous Solid Acid Catalysts
    Xie, Junkang
    Han, Qiaoning
    Wang, Jing
    Bai, Lijuan
    Lu, Jianfang
    Liu, Zuguang
    [J]. INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2019, 58 (49) : 22202 - 22211
  • [6] SYNTHESIS OF TERPINEOL FROM alpha-PINENE CATALYZED BY TCA/Y-ZEOLITE
    Wijayati, Nanik
    Pranowo, Harno Dwi
    Jumina
    Triyono
    [J]. INDONESIAN JOURNAL OF CHEMISTRY, 2011, 11 (03) : 234 - 237
  • [7] Low-price guarantees and pricing behavior: evidence from hypermarkets in Korea
    Chung, Hoe Sang
    Kim, Min
    [J]. ECONOMICS BULLETIN, 2016, 36 (02): : 1223 - +
  • [8] Commercial turpentine oil enriched with α-terpineol using an acid heterogeneous catalyst
    de Jesus Aguas-Caballero, Ivan
    Villa-Holguin, Aida Luz
    Alarcon-Durango, Edwin Alexis
    [J]. REVISTA FACULTAD DE INGENIERIA-UNIVERSIDAD DE ANTIOQUIA, 2024, (112): : 78 - 85
  • [9] Synthesis of terpinyl acetate from α-pinene catalyzed by α-hydroxycarboxylic acid-boric acid composite catalyst
    Meng, Zhonglei
    Qin, Rongxiu
    Wen, Rusi
    Xie, Junkang
    Li, Guiqing
    Zhou, Yonghong
    [J]. PLOS ONE, 2024, 19 (04):
  • [10] How to protect your premium product from low-price competitors: Price, quality, or portfolio adjustment?
    Jost, Peter-J.
    [J]. INTERNATIONAL JOURNAL OF RESEARCH IN MARKETING, 2014, 31 (03) : 253 - 265
12345