Synthesis of Terpineol from α-Pinene Using Low-Price Acid Catalyst

被引：26

作者：

Prakoso, Tirto ^{[1
,2
]}

Hanley, Jonathan ^{[1
]}

Soebianta, Mellisa Nathania ^{[1
]}

Soerawidjaja, Tatang Hernas ^{[1
,2
]}

Indarto, Antonius ^{[1
,2
]}

机构：

[1] Inst Teknol Bandung, Chem Engn Dept, Labtek 10,Kampus ITB,Jalan Ganesha 10, Bandung 40132, Indonesia

[2] Inst Teknol Bandung, Bioenergy & Chemurgy Engn Dept, Kampus ITB Jatinangor, Kabupaten Sumedang 45363, Indonesia

来源：

CATALYSIS LETTERS | 2018年 / 148卷 / 02期

关键词：

alpha-Pinene; Terpineol; One-stage reaction; Hydration; Acid catalyst;

D O I：

10.1007/s10562-017-2267-2

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

This study aims to produce terpineol from alpha-pinene by direct one-stage hydration reaction mechanism. The study was focused to investigate the influence of organic acids and mixture acid catalyst between organic acid and phosphoric acid. Based on the experimental results and depending on the acid strength and affinity of catalyst to the carbocation mechanism, p-toluensulfonic acid was shown to have a better result compared to acetic and formic acid. The presence of phosphoric acid could boost the performance of acetic acid in term of acidity strength that increased the conversion of the reaction. The highest yield of terpineol from alpha-pinene in this hydration reaction in this study was 53.5 wt% using mixed phosphoric and acetic acid. Graphical Abstract [GRAPHICS] .

引用

页码：725 / 731

页数：7

共 50 条

[41] Phosphotungstic acid as a versatile catalyst for the synthesis of fragrance compounds by α-pinene oxide isomerization:: Solvent-induced chemoselectivity
Rocha, Kelly A. da Silva
Hoehne, Juliana L.
Gusevskaya, Elena V.
[J]. CHEMISTRY-A EUROPEAN JOURNAL, 2008, 14 (20) : 6166 - 6172
[42] Biosynthesis of 4-isopropylbenzoic acid from -pinene by using a mutant strain originated from the -pinene degrader Pseudomonas veronii ZW
Cheng, Zhuowei
Tao, Jinguo
Ye, Jiexu
Li, Chao
Zhang, Xiaomin
Chen, Jianmeng
[J]. JOURNAL OF CHEMICAL TECHNOLOGY AND BIOTECHNOLOGY, 2018, 93 (01) : 54 - 62
[43] SYNTHESIS OF TRIBUTYL CITRATE USING SOLID ACID AS A CATALYST
Xu, J.
Jiang, J.
Wei, L. V.
Gao, Y.
[J]. CHEMICAL ENGINEERING COMMUNICATIONS, 2011, 198 (04) : 474 - 482
[44] SIMPLE SYNTHESIS OF HEXAHYDROCANNABINOIDS USING PHENYLBORIC ACID CATALYST
MURPHY, WS
TULADHAR, SM
DUFFY, B
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1992, (05): : 605 - 609
[45] An efficient synthesis of tetrahydrocarbazole using solid acid catalyst
Abdul, Majid Sheikh
Ahmad, Khanday Waheed
Radha, Tomar
[J]. RESEARCH JOURNAL OF CHEMISTRY AND ENVIRONMENT, 2013, 17 (07): : 62 - 67
[46] Synthesis of Tributyl Citrate Using Preyssler Acid as Catalyst
Lu, Yun
Xu, Shengxian
Zhao, Feng
[J]. 2016 INTERNATIONAL CONFERENCE ON MATERIALS SCIENCE, RESOURCE AND ENVIRONMENTAL ENGINEERING, 2017, 1794
[47] Enantioselective synthesis of a drug for a low price using open science
Woelfle, Michael
Todd, Matthew H.
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2010, 240
[48] A practical synthesis of d-α-terpineol via Markovnikov addition of d-limonene using trifluoroacetic acid
Yuasa, Yoshifumi
Yuasa, Yoko
[J]. ORGANIC PROCESS RESEARCH & DEVELOPMENT, 2006, 10 (06) : 1231 - 1232
[49] Prins condensation for synthesis of nopol from P-pinene and paraformaldehyde on novel Fe-Zn double metal cyanide solid acid catalyst
Patil, Mallikarjun V.
Yadav, Mukesh K.
Jasra, Raksh V.
[J]. JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2007, 273 (1-2) : 39 - 47
[50] Optimum Synthesis of Myrtenal from α-Pinene by Photosensitized Oxidation Using Orthogonal Design
Zou, Binbin
Chen, Qianwen
Luo, Weihua
Wang, Guiwu
[J]. ADVANCED MATERIALS AND ENGINEERING APPLICATIONS, 2012, 161 : 148 - 152

← 1 2 3 4 5 →