Synthesis of Terpineol from α-Pinene Using Low-Price Acid Catalyst

被引：26
|
作者：
Prakoso, Tirto [1 ,2 ]
Hanley, Jonathan [1 ]
Soebianta, Mellisa Nathania [1 ]
Soerawidjaja, Tatang Hernas [1 ,2 ]
Indarto, Antonius [1 ,2 ]
机构：
[1] Inst Teknol Bandung, Chem Engn Dept, Labtek 10,Kampus ITB,Jalan Ganesha 10, Bandung 40132, Indonesia
[2] Inst Teknol Bandung, Bioenergy & Chemurgy Engn Dept, Kampus ITB Jatinangor, Kabupaten Sumedang 45363, Indonesia
来源：
CATALYSIS LETTERS | 2018年 / 148卷 / 02期
关键词：
alpha-Pinene; Terpineol; One-stage reaction; Hydration; Acid catalyst;
D O I：
10.1007/s10562-017-2267-2
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
This study aims to produce terpineol from alpha-pinene by direct one-stage hydration reaction mechanism. The study was focused to investigate the influence of organic acids and mixture acid catalyst between organic acid and phosphoric acid. Based on the experimental results and depending on the acid strength and affinity of catalyst to the carbocation mechanism, p-toluensulfonic acid was shown to have a better result compared to acetic and formic acid. The presence of phosphoric acid could boost the performance of acetic acid in term of acidity strength that increased the conversion of the reaction. The highest yield of terpineol from alpha-pinene in this hydration reaction in this study was 53.5 wt% using mixed phosphoric and acetic acid. Graphical Abstract [GRAPHICS] .
引用
收藏
页码：725 / 731
页数：7
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