Preparation of polymer gel dosimeters for low gamma irradiation dose

被引:2
|
作者
El-Kelany, Moushera A. [2 ]
Khozemy, Ehab E. [1 ]
Goda, Heba [3 ]
Awad, Boshra [3 ]
机构
[1] Egyptian Atom Energy Author, Natl Ctr Radiat Res & Technol, Polymer Chem Dept, Cairo, Egypt
[2] Egyptian Atom Energy Author, Natl Ctr Radiat Res & Technol, Radiat Protect & Dosimetry Dept, Cairo, Egypt
[3] Ain Shams Univ, Fac Women Arts Sci & Educ, Chem Dept, Cairo, Egypt
关键词
CMC; gelatin; hydrogels; irradiation dosimeter; PVA; CONGO RED-DYE; CROSS-LINKING; RADIATION; GELATIN; DEGRADATION; CARBOXYMETHYLCELLULOSE; HYDROGELS;
D O I
10.1515/ract-2022-0106
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
In this study, two separate hydrogel dosimeters were prepared for low-dose measurement. The first system is based on Congo Red (CR) dye and a blend of natural polymers (gelatin/CMC) while the second system is based on 2,6-dichlorophenol indophenol (DCP) blue dye and a hybrid polymer blend (PVA/gelatin/CMC). The sensitivity of Congo red (CR)-(gelatin/CMC) gel dosimeter and 2, 6 - di choro phenol indophenols(DCP)-(PVA/gelatin/CMC) gel dosimetry systems were examined by studying the comparative results between the two different systems through the change in optical properties upon exposure to different gamma radiation doses, which showed the sensitivity of the second system (DCP)-(PVA/gelatin/CMC) to radiation is more than the first system(CR)-(gelatin/CMC) (CR) and (DCP)dyes have absorbance crest at 492 and 622 nm respectively. With the increase of the radiation dose, the decomposition of the dyes increases, and thus the color of the prepared hydrogel changes from orange to colorless in the case of (CR) dye at the dose (0-3.5 kGy) and from blue to colorless in the case (DCP) dye at the absorbed doses ranged from (0-1000 Gy). Dose-response curves, sensitivity, FTIR analysis, and the relative stability of the prepared hydrogel before and after irradiation were studied.
引用
收藏
页码:195 / 202
页数:8
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