A synthetic cycle for iminophosphorane synthesis involving direct intermolecular N=P bond formation on N2-derived molybdenum nitride

被引：0
|
作者：
Jin, Li [1 ]
Zhang, Guoqiang [1 ]
Yang, Xiaoqin [2 ]
Song, Jinyi [1 ]
Wang, Jin [2 ]
Liao, Qian [1 ]
机构：
[1] Dalian Univ Technol, Zhang Dayu Sch Chem, 2 Linggong Rd, Dalian 116024, Liaoning, Peoples R China
[2] Yancheng Teachers Univ, Jiangsu Prov Engn Res Ctr Tumor Targeted Nano Diag, Sch Pharm, Yancheng 224007, Jiangsu, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 51期
基金：
中国国家自然科学基金;
关键词：
Molybdenum compounds - Phosphorus compounds;
D O I：
10.1039/d3cc01925j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
NP bonds were built straightforwardly between N-2-derived molybdenum terminal nitride and phosphines. Subsequent PCET, oxidative decarbonylation and then reduction regenerated the N-2 complex, developing a synthetic cycle transferring N-2 into various iminophosphoranes. Both aryl and alkyl substituted phosphines proceeded smoothly.
引用
收藏
页码：7955 / 7958
页数：4
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