A synthetic cycle for iminophosphorane synthesis involving direct intermolecular N=P bond formation on N2-derived molybdenum nitride

被引：0

作者：

Jin, Li ^{[1
]}

Zhang, Guoqiang ^{[1
]}

Yang, Xiaoqin ^{[2
]}

Song, Jinyi ^{[1
]}

Wang, Jin ^{[2
]}

Liao, Qian ^{[1
]}

机构：

[1] Dalian Univ Technol, Zhang Dayu Sch Chem, 2 Linggong Rd, Dalian 116024, Liaoning, Peoples R China

[2] Yancheng Teachers Univ, Jiangsu Prov Engn Res Ctr Tumor Targeted Nano Diag, Sch Pharm, Yancheng 224007, Jiangsu, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2023年 / 59卷 / 51期

基金：

中国国家自然科学基金;

关键词：

Molybdenum compounds - Phosphorus compounds;

D O I：

10.1039/d3cc01925j

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

NP bonds were built straightforwardly between N-2-derived molybdenum terminal nitride and phosphines. Subsequent PCET, oxidative decarbonylation and then reduction regenerated the N-2 complex, developing a synthetic cycle transferring N-2 into various iminophosphoranes. Both aryl and alkyl substituted phosphines proceeded smoothly.

引用

页码：7955 / 7958

页数：4

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