Efficient CO Oxidation by Co/Ta2O5 Prepared by Deposition-Precipitation with Urea

被引:0
|
作者
Xia, Qing [1 ]
Qin, Haijian [1 ]
Xia, Feifei [1 ]
Yao, Pengfei [1 ]
Zheng, Chunzhi [1 ]
Zhao, Songjian [1 ]
Zhang, Huabing [2 ]
Yang, Fengli [1 ]
机构
[1] Jiangsu Univ Technol, Sch Resources & Environm Engn, Changzhou 213001, Jiangsu, Peoples R China
[2] Panzhihua Univ, Sch Biol & Chem Engn, Panzhihua 617000, Peoples R China
关键词
CO oxidation; Co/Ta2O5; Deposition-precipitation method with urea; CATALYSTS; PERFORMANCE; REACTIVITY; COBALT; TA2O5; CO3O4; OXIDE; TRANSITION;
D O I
10.1007/s10562-023-04551-4
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
CO oxidation at mild condition is significant for industrial process but still challenging nowadays, especially for the non-noble metal catalysts. The preparation method significant affect the catalytic activity of the catalyst. Comparing with cobalt supported on tantalum oxide prepared by impregnation method, Co/Ta2O5 prepared by deposition-precipitation method with urea in this study has smaller particle size, higher specific surface area and better redox properties, and these features make the catalyst exhibit higher catalytic activity for CO oxidation at mild condition. 90% CO conversion was achieved at 130 degree celsius, and CO was fully converted at 150 degree celsius. The XPS and DRIFTs results show that Co/Ta2O5 has more oxygen vacancies, and the absorbed CO will react with oxygen. The study may provide a new thought for the preparation of catalysts with high activity at mild condition.
引用
收藏
页码:3174 / 3183
页数:10
相关论文
共 50 条
  • [21] Properties of Ta2O5 thin films prepared by ion-assisted deposition
    Farhan, Mansour S.
    Zalnezhad, E.
    Bushroa, A. R.
    MATERIALS RESEARCH BULLETIN, 2013, 48 (10) : 4206 - 4209
  • [22] Au-Ir/TiO2 Prepared by Deposition Precipitation with Urea: Improved Activity and Stability in CO Oxidation
    Gomez-Cortes, Antonio
    Diaz, Gabriela
    Zanella, Rodolfo
    Ramirez, Humberto
    Santiago, Patricia
    Saniger, Jose M.
    JOURNAL OF PHYSICAL CHEMISTRY C, 2009, 113 (22): : 9710 - 9720
  • [23] Halide chemical vapour deposition of Ta2O5
    Department of Inorganic Chemistry, Ångström Laboratory, University of Uppsala, SE-751 21, Uppsala, Sweden
    Thin Solid Films, (111-114):
  • [24] Hydrogenation of CO2 over a rice husk ash supported nickel catalyst prepared by deposition-precipitation
    Chang, FW
    Hsiao, TJ
    Shih, JD
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 1998, 37 (10) : 3838 - 3845
  • [25] Halide chemical vapour deposition of Ta2O5
    Forsgren, K
    Hårsta, A
    THIN SOLID FILMS, 1999, 343 : 111 - 114
  • [26] Highly reproducible syntheses of active Au/TiO2 catalysts for CO oxidation by deposition-precipitation or impregnation
    Li, WC
    Comotti, M
    Schüth, F
    JOURNAL OF CATALYSIS, 2006, 237 (01) : 190 - 196
  • [27] Preferential CO oxidation in H2-rich stream over Au/CeO2 catalysts prepared via modified deposition-precipitation
    Sakwarathorn, Theerathad
    Luengnaruemitchai, Apanee
    Pongstabodee, Sangobtip
    JOURNAL OF INDUSTRIAL AND ENGINEERING CHEMISTRY, 2011, 17 (04) : 747 - 754
  • [28] Optical properties and microstructure of Ta2O5 thin films prepared by oblique angle deposition
    肖秀娣
    董国平
    贺洪波
    齐红基
    范正修
    邵建达
    Chinese Optics Letters, 2009, 7 (10) : 967 - 970
  • [29] Research on the Properties of Ta2O5 Optical Films Prepared with APS Plasma Assisted Deposition
    Pan Yong-gang
    Liu Zheng
    Liu Wen-cheng
    Li Mian
    Zhang Si-bao
    Luo Chang-xin
    Zhang Chun-juan
    SEVENTH ASIA PACIFIC CONFERENCE ON OPTICS MANUFACTURE (APCOM 2021), 2022, 12166
  • [30] Optical properties and microstructure of Ta2O5 thin films prepared by oblique angle deposition
    Xiao, Xiudi
    Dong, Guoping
    He, Hongbo
    Qi, Hongji
    Fan, Zhengxiu
    Shao, Jianda
    CHINESE OPTICS LETTERS, 2009, 7 (10) : 967 - 970