Construction of Benzo-Fused Polycyclic Heteroaromatic Compounds through Palladium-Catalyzed Intramolecular C-H/C-H Biaryl Coupling

被引：6

作者：

Nishii, Yuji ^{[1
]}

Miura, Masahiro ^{[2
]}

机构：

[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Osaka 5650871, Japan

[2] Osaka Univ, Inst Open & Transdisciplinary Res Initiat ICS OTRI, Innovat Catalysis Sci Div, Osaka 5650871, Japan

来源：

CATALYSTS | 2023年 / 13卷 / 01期

基金：

日本学术振兴会;

关键词：

C-H; C-H coupling; dibenzofuran; carbazole; dibenzothiophene; palladium; RING-CLOSURE; CYCLIZATION; ARYLATION; ANALOGS;

D O I：

10.3390/catal13010012

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Dibenzo-fused five-membered heteroaromatic compounds, including dibenzofuran, carbazole, and dibenzothiophene, are fundamental structural units in various important polycyclic heteroaromatic compounds. The intramolecular C-H/C-H biaryl coupling of diaryl (thio)ethers and amines based on palladium(II) catalysis under oxidative conditions is known to be one of the most effective, step-economic methods for their construction. Representative examples for the construction of structurally intriguing pi-extended polycyclic heteroaromatics through catalytic coupling reactions are briefly summarized in this mini-review.

引用

页数：10

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