Construction of Benzo-Fused Polycyclic Heteroaromatic Compounds through Palladium-Catalyzed Intramolecular C-H/C-H Biaryl Coupling

被引：6
|
作者：
Nishii, Yuji [1 ]
Miura, Masahiro [2 ]
机构：
[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Osaka 5650871, Japan
[2] Osaka Univ, Inst Open & Transdisciplinary Res Initiat ICS OTRI, Innovat Catalysis Sci Div, Osaka 5650871, Japan
来源：
CATALYSTS | 2023年 / 13卷 / 01期
基金：
日本学术振兴会;
关键词：
C-H; C-H coupling; dibenzofuran; carbazole; dibenzothiophene; palladium; RING-CLOSURE; CYCLIZATION; ARYLATION; ANALOGS;
D O I：
10.3390/catal13010012
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Dibenzo-fused five-membered heteroaromatic compounds, including dibenzofuran, carbazole, and dibenzothiophene, are fundamental structural units in various important polycyclic heteroaromatic compounds. The intramolecular C-H/C-H biaryl coupling of diaryl (thio)ethers and amines based on palladium(II) catalysis under oxidative conditions is known to be one of the most effective, step-economic methods for their construction. Representative examples for the construction of structurally intriguing pi-extended polycyclic heteroaromatics through catalytic coupling reactions are briefly summarized in this mini-review.
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页数：10
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