Palladium-Catalyzed C-H Acetoxylation Reations

被引：10
|
作者：
Chen, Tianbao [1 ]
Zhang, Ming [1 ]
机构：
[1] Jiangxi Normal Univ, Coll Chem & Chem Engn, Nanchang 330022, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2015年 / 35卷 / 04期
基金：
中国国家自然科学基金;
关键词：
palladium; catalysis; acetoxylation; DIRECTING GROUPS; OXIDATION; FUNCTIONALIZATION; ACID; BONDS; CONSTRUCTION; OXYGENATION; DERIVATIVES; ACTIVATION; SCAFFOLDS;
D O I：
10.6023/cjoc201409022
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium-catalyzed C-H functionalization is one of the hot topics in the field of organic synthesis methodology. Mild and selective transformation of this type will undoubtedly find widespread application across the chemistry. Even though Pd-catalyzed reaction has been deeply developed over past decades, it remains to be a huge challenge in organic chemistry. Herein, this review presents the recent progress for palladium-catalyzed C(sp(2))-H and C(sp(3))-H acetoxylation and their applications in the synthesis of complex molecules. Moreover, the research trend of this area is also prospected.
引用
收藏
页码：813 / 826
页数：14
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