A TiO2 nanorod and perylene diimide based inorganic/organic nanoheterostructure photoanode for photoelectrochemical urea oxidation

Visible light-driven photoelectrochemical (PEC) urea oxidation using inorganic/organic nano-heterostructure (NH) photoanodes is an attractive method for hydrogen (H-2) production. In this article, inorganic/organic NHs (TiO2/PDIEH) consisting of a N,N-bis(2-ethylhexyl)perylene-3,4,9,10-tetracarboxylic diimide (PDIEH) thin layer over TiO2 nanorods (NRs) were fabricated for the PEC urea oxidation reaction (UOR). In these NHs, a PDIEH layer was anchored on TiO2 NR arrays using the spin-coating technique, which is beneficial for the uniform deposition of PDIEH on TiO2 NRs. Uniform deposition facilitated adequate interface contact between PDIEH and TiO2 NRs. TiO2/PDIEH NHs achieved a high current density of 1.1 mA cm(-2) at 1.96 V-RHE compared to TiO2 NRs. TiO2/PDIEH offers long-term stability under light illumination with 90.21% faradaic efficiency. TiO2/PDIEH exhibits a solar-to-hydrogen efficiency of 0.52%. This outcome opens up new opportunities for inorganic/organic NHs for high-performance PEC urea oxidation.