Reaction of 4,6-Di-tert-butyl-3-nitrocyclohexa-3,5-diene-1,2-dione with Secondary Amines

被引:0
|
作者
Ivakhnenko, E. P. [1 ]
Malai, V. I. [1 ]
Demidov, O. P. [2 ]
Minkin, V. I. [1 ]
机构
[1] Southern Fed Univ, Inst Phys & Organ Chem, Rostov Na Donu 344090, Russia
[2] North Caucasus Fed Univ, Stavropol 355029, Russia
基金
俄罗斯科学基金会;
关键词
nitroquinone; o-quinone; secondary amines; ANRORC; Michael addition; PRODUCTS;
D O I
10.1134/S1070428023080043
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The reaction of 4,6-di-tert-butyl-3-nitrocyclohexa-3,5-diene-1,2-dione with secondary amines (piperidine, morpholine, 1-methylpiperazine) in isopropanol involves Michael addition and ANRORC and forms a mixture of products. The resulting compounds were characterized by IR and H-1 and C-13 NMR spectroscopy, and elemental analysis. The molecular structures of 3-nitrocyclohexa-3-ene-1,2-dione and cyclopenta-1,3-diene derivatives were established by X-ray diffraction analysis.
引用
收藏
页码:1315 / 1321
页数:7
相关论文
共 50 条
  • [31] New Data on the Reaction of Diethyl Hydrogen Phosphite with 3,5-Di-tert-butyl-4-hydroxybenzaldehyde
    R. K. Ismagilov
    V. V. Moskva
    L. Yu. Mosunova
    A. S. Romakhin
    Russian Journal of General Chemistry, 2001, 71 : 1547 - 1549
  • [32] Reaction of 3,5-di-tert-butyl-4-hydroxybenzylidene chloride with P(III) acid esters
    Gazizov, MB
    Ismagilov, RK
    Shamsutdinova, LM
    Karimova, RF
    Sinyashin, OG
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2005, 75 (12) : 1971 - 1972
  • [33] Crystal structure of dimethyl 3,4,5,6-tetraphenylcyclohexa-3,5-diene-1,2-dicarboxylate
    Greenberg, Fred H.
    Nazarenko, Alexander Y.
    ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 : 947 - +
  • [34] Reaction of 3-halogenated cis-cyclohexa-3,5-diene-1,2-diol derivatives with Pd on charcoal
    Lee, SH
    Cheong, CS
    BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2000, 21 (11) : 1061 - 1062
  • [35] Reactions of 3,5-di-tert-butyl-1,2-benzoquinone with mercapto carboxylic acids
    L. Yu. Ukhin
    K. Yu. Suponitsky
    E. N. Shepelenko
    L. V. Belousova
    D. V. Alekseenko
    G. S. Borodkin
    L. N. Etmetchenko
    Russian Chemical Bulletin, 2016, 65 : 727 - 730
  • [36] Oxidation of Group II Metals with 3,5-Di-tert-butyl-1,2-benzoquinone
    A. V. Piskunov
    S. V. Maslennikov
    V. K. Cherkasov
    I. V. Spirina
    V. P. Maslennikov
    Russian Journal of General Chemistry, 2002, 72 : 933 - 938
  • [37] Reaction of quinaldine with 4,6-di (tert-butyl)-3-nitro-1,2-benzoquinone. Dependence of the outcome on the reaction conditions and a deeper insight into the mechanism
    Krasnikova, Tatyana A.
    Sayapin, Yurii A.
    Tupaeva, Inna O.
    Gusakov, Eugeny A.
    Ozhogin, Ilya V.
    Lisovin, Anton V.
    Nikogosov, Mikhail V.
    Demidov, Oleg P.
    Bang, Duong Nghia
    Lam, Tran Dai
    Trang, Nguyen Thi Thu
    Dubonosov, Alexander D.
    Minkin, Vladimir I.
    HELIYON, 2023, 9 (06)
  • [38] Oxidation of Group II metals with 3,5-di-tert-butyl-1,2-benzoquinone
    Piskunov, AV
    Maslennikov, SV
    Cherkasov, VK
    Spirina, IV
    Maslennikov, VP
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2002, 72 (06) : 933 - 938
  • [39] HYPOLIPEMIC PROPERTIES OF 3,5-DI-TERT-BUTYL-4-HYDROXYMERCAPTOPHENOL DERIVATIVES
    WAGNER, ER
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1975, (169): : 33 - 33
  • [40] REDOX CHARACTERISTICS OF 3,5-DI-TERT BUTYL-4-HYDROXYBENZYLIDENEMALONITRILE
    RIESER, J
    ABOUELENIEN, G
    WALLENFELS, K
    TETRAHEDRON LETTERS, 1977, (39) : 3461 - 3464