Synthesis of CF3-substituted isoindolones via rhodium(III)-catalyzed carbenoid C-H functionalization of aryl hydroxamates

被引：4
|
作者：
Vorobyeva, Daria V. [1 ]
Bubnova, Alexandra S. [1 ]
Buyanovskaya, Anastasiya G. [1 ]
Osipov, Sergey N. [1 ]
机构：
[1] Russian Acad Sci, A N Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2023年 / 33卷 / 01期
基金：
俄罗斯科学基金会;
关键词：
aryl hydroxamates; C-H activation; diazo compounds; rhodium(III) catalysis; isoindolones; organofluorine compounds; ACID-DERIVATIVES; CYCLOADDITION; ACCESS; ISOINDOLINONES; INHIBITORS; ALKENES;
D O I：
10.1016/j.mencom.2023.01.010
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient method for the selective preparation of trifluoro-methyl-substituted isoindolones has been developed via Rh-III-catalyzed C-H activation/[4 + 1]-annulation of aryl hydroxamates with functionalized acceptor/acceptor diazo compounds as cross-coupling partners.
引用
收藏
页码：34 / 36
页数：3
相关论文
共 50 条
  • [41] Synthesis of substituted oxindoles from α-chloroacetanilides via palladium-catalyzed C-H functionalization
    Hennessy, EJ
    Buchwald, SL
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (40) : 12084 - 12085
  • [42] Rhodium(III)-catalyzed chemoselective C-H functionalization of benzamides with methyleneoxetanones controlled by the solvent
    Bian, Mengyao
    Ma, Kuangshun
    Mawjuda, Hamdulla
    Yu, Xiyong
    Li, Xingwei
    Gao, Hui
    Zhou, Zhi
    Yi, Wei
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2019, 17 (25) : 6114 - 6118
  • [43] Rh-Catalyzed C-H alkylation enabling modular synthesis of CF3-substituted benzannulated macrocyclic inhibitors of B cell responses
    Sun, Tao
    He, Shijun
    Xu, Zhongliang
    Zuo, Jianping
    Yu, Yang
    Yang, Weibo
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2021, 19 (16) : 3589 - 3594
  • [44] Rhodium(III)-Catalyzed Diastereoselective Synthesis of 1-Aminoindanes via C-H Activation
    Han, Sang Hoon
    Mishra, Neeraj Kumar
    Jeon, Mijin
    Kim, Saegun
    Kim, Hyung Sik
    Jung, Seung-Young
    Jung, Young Hoon
    Ku, Jin-Mo
    Kim, In Su
    ADVANCED SYNTHESIS & CATALYSIS, 2017, 359 (22) : 3900 - 3904
  • [45] Rhodium(iii)-catalyzed synthesis of trisubstituted furans via vinylic C-H bond activation
    Sherikar, Mahadev Sharanappa
    Bettadapur, Kiran R.
    Lanke, Veeranjaneyulu
    Prabhu, Kandikere Ramaiah
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2021, 19 (34) : 7470 - 7474
  • [46] Naphthol synthesis: annulation of nitrones with alkynes via rhodium(III)-catalyzed C-H activation
    Wang, Qiang
    Xu, Youwei
    Yang, Xifa
    Li, Yunyun
    Li, Xingwei
    CHEMICAL COMMUNICATIONS, 2017, 53 (69) : 9640 - 9643
  • [47] Synthesis of Mesoionic Isoquinolines by Rhodium(III)-Catalyzed C-H Activation
    Zhang, Wei
    Wang, Cheng-Qi
    Lin, Hui
    Dong, Lin
    Xu, Yan-Jun
    CHEMISTRY-A EUROPEAN JOURNAL, 2016, 22 (03) : 907 - 910
  • [48] Asymmetric Synthesis of α-Branched Amines via Rh(III)-Catalyzed C-H Bond Functionalization
    Wangweerawong, Apiwat
    Bergman, Robert G.
    Ellman, Jonathan A.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (24) : 8520 - 8523
  • [49] Quinazoline Synthesis via Rh(III)-Catalyzed Intermolecular C-H Functionalization of Benzimidates with Dioxazolones
    Wang, Jie
    Zha, Shanke
    Chen, Kehao
    Zhang, Feifei
    Song, Chao
    Zhu, Jin
    ORGANIC LETTERS, 2016, 18 (09) : 2062 - 2065
  • [50] Ir(III)-Catalyzed C-H Functionalization of Triphenylphosphine Oxide toward 3-Aryl Oxindoles
    Lou, Qin-Xin
    Niu, Yuan
    Qi, Zhi-Chao
    Yang, Shang-Dong
    JOURNAL OF ORGANIC CHEMISTRY, 2020, 85 (22): : 14527 - 14536
12345