Synthesis of CF3-substituted isoindolones via rhodium(III)-catalyzed carbenoid C-H functionalization of aryl hydroxamates

被引：4
|
作者：
Vorobyeva, Daria V. [1 ]
Bubnova, Alexandra S. [1 ]
Buyanovskaya, Anastasiya G. [1 ]
Osipov, Sergey N. [1 ]
机构：
[1] Russian Acad Sci, A N Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia
来源：
MENDELEEV COMMUNICATIONS | 2023年 / 33卷 / 01期
基金：
俄罗斯科学基金会;
关键词：
aryl hydroxamates; C-H activation; diazo compounds; rhodium(III) catalysis; isoindolones; organofluorine compounds; ACID-DERIVATIVES; CYCLOADDITION; ACCESS; ISOINDOLINONES; INHIBITORS; ALKENES;
D O I：
10.1016/j.mencom.2023.01.010
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient method for the selective preparation of trifluoro-methyl-substituted isoindolones has been developed via Rh-III-catalyzed C-H activation/[4 + 1]-annulation of aryl hydroxamates with functionalized acceptor/acceptor diazo compounds as cross-coupling partners.
引用
收藏
页码：34 / 36
页数：3
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