Diamond epitaxial growth by gas-source molecular beam epitaxy with pure methane

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作者
Nishimori, T. [1 ]
Sakamoto, H. [1 ]
Takakuwa, Y. [1 ]
Kono, Sh. [1 ]
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[1] Mitsubishi Heavy Industries, Ltd, Yokohama, Japan
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Activation energy - Carbon - Desorption - Methane - Molecular beam epitaxy - Substrates - Vapor phase epitaxy;
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摘要
Diamond epitaxial films with a thickness of 200-350 A have been successfully grown on C(100) surfaces by gas-source molecular beam epitaxy (GSMBE) with methane without addition of hydrogen or oxygen. The activation energy was measured by a selective growth method using Ta-patterned substrates to be 15 kcal/mol. This value is close to the activation energy of H2 desorption on C(100), suggesting that the diamond epitaxial growth rate by this GSMBE is limited by hydrogen desorption.
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