Copper-Catalyzed Hydrogen Production through the Dehydrogenative Coupling of Methanol and Diamine

被引：0

作者：

Cheng, Danyang ^{[1
]}

Yu, Shixiang ^{[1
]}

Wang, Meng ^{[1
]}

Ma, Ding ^{[1
]}

机构：

[1] Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, New Cornerstone Sci Lab, Beijing 100871, Peoples R China

来源：

PRECISION CHEMISTRY | 2024年 / 2卷 / 04期

基金：

中国国家自然科学基金; 国家重点研发计划;

关键词：

methanol reforming; hydrogen release; aminocarbonylation; dehydrogenative coupling; Cu/ZnO/Al2O3; catalyst; CARBON-DIOXIDE; CARRIER; STORAGE; CO2;

D O I：

10.1021/prechem.3c00113

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A hydrogen storage system was developed via heterogeneous catalysis, employing the dehydrogenative coupling of methanol and N,N '-dimethylethylenediamine to efficiently produce high-purity H-2. In this process, the Cu/ZnO/Al2O3 catalyst displayed superior activity in hydrogen production, with Cu+ identified as the major active site through comprehensive characterization.

引用

页码：138 / 142

页数：5

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