Copper-Catalyzed Hydrogen Production through the Dehydrogenative Coupling of Methanol and Diamine

被引：0
|
作者：
Cheng, Danyang [1 ]
Yu, Shixiang [1 ]
Wang, Meng [1 ]
Ma, Ding [1 ]
机构：
[1] Peking Univ, Coll Chem & Mol Engn, Beijing Natl Lab Mol Sci, New Cornerstone Sci Lab, Beijing 100871, Peoples R China
来源：
PRECISION CHEMISTRY | 2024年 / 2卷 / 04期
基金：
中国国家自然科学基金; 国家重点研发计划;
关键词：
methanol reforming; hydrogen release; aminocarbonylation; dehydrogenative coupling; Cu/ZnO/Al2O3; catalyst; CARBON-DIOXIDE; CARRIER; STORAGE; CO2;
D O I：
10.1021/prechem.3c00113
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A hydrogen storage system was developed via heterogeneous catalysis, employing the dehydrogenative coupling of methanol and N,N '-dimethylethylenediamine to efficiently produce high-purity H-2. In this process, the Cu/ZnO/Al2O3 catalyst displayed superior activity in hydrogen production, with Cu+ identified as the major active site through comprehensive characterization.
引用
收藏
页码：138 / 142
页数：5
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