SYNTHESIS AND STRUCTURAL CHARACTERIZATION OF THE MIXED LITHIUM MAGNESIUM AMIDE, [(PHCH2(ME2NCH2CH2)N)4LI2MG] - A NEW-TYPE OF MAGNESIATE COMPLEX FREE OF A DONOR SOLVENT AS LIGAND

被引：16

作者：

CLEGG, W

HENDERSON, KW

MULVEY, RE

ONEIL, PA

机构：

[1] UNIV STRATHCLYDE, DEPT PURE & APPL CHEM, GLASGOW G1 1XL, SCOTLAND

[2] UNIV NEWCASTLE UPON TYNE, DEPT CHEM, NEWCASTLE UPON TYNE NE1 7RU, TYNE & WEAR, ENGLAND

来源：

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS | 1993年 / 11期

关键词：

D O I：

10.1039/c39930000969

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A mixture of the alkyl(amido)magnesium compound, [PhCH2(Me2NCH2CH2)NMgBun], the secondary amine, [PhCH2(Me2NCH2CH2)NH], and the alkyl lithium, (Bu(n)Li), produces the lithium amidomagnesiate, [{PhCH2(Me2NCH2CH2)N}4Li2Mg] which is shown by an X-ray diffraction study to have intramolecular (tertiary amine) N-Li coordinations in the solid state.

引用

页码：969 / 970

页数：2

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