Synthesis and structural characterization of the homoleptic magnesium bis zincate complex Mg(thf)(6)[Zn(CH2Ph)(3)](2)

被引：12

作者：

Rijnberg, E

Jastrzebski, JTBH

Boersma, J

Kooijman, H

Spek, AL

vanKoten, G

机构：

[1] UNIV UTRECHT,DEBYE INST,DEPT MET MEDIATED SYNTH,NL-3584 CH UTRECHT,NETHERLANDS

[2] UNIV UTRECHT,BIJVOET CTR BIOMOL RES CRYSTAL & STRUCT CHEM,NL-3584 CH UTRECHT,NETHERLANDS

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1997年 / 541卷 / 1-2期

关键词：

anionic complex; magnesium; organozinc; zincate;

D O I：

10.1016/S0022-328X(97)00050-8

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The addition of Mg(CH2Ph)(2)(thf)(2) to a thf solution of Zn(CH2Ph)(2) yields the zincate complex Mg(thf)(6)[Zn(CH2Ph)(3)](2) (1), which has been characterized by X-ray crystallography and NMR. Complex 1 is cleaved by tmeda into a 1:2 mixture of Mg(CH2Ph)(2)(tmeda) and Zn(CH2Ph)(2)(tmeda). (C) 1997 Elsevier Science S.A.

引用

页码：181 / 185

页数：5

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