SOLVENT-FREE SYNTHESIS OF TETRAMETHYLAMMONIUM SALTS - SYNTHESIS AND CHARACTERIZATION OF [N(CH3)(4)](2)[C2O4], [N(CH3)(4)][CO3CH4], [N(CH3)(4)][NO2], [N(CH3)(4)][CO2H], AND [N(CH3)(4)][O2C(CH2)(2)CO2CH3]

被引：13

作者：

ALBERT, B ^{[1
]}

JANSEN, M ^{[1
]}

机构：

[1] UNIV BONN,INST ANORGAN CHEM,D-53121 BONN,GERMANY

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 1995年 / 621卷 / 10期

关键词：

TETRAMETHYLAMMONIUM SALTS; SOLVENT-FREE SYNTHESIS; OXALATE; METHYLCARBONATE; NITRITE; FORMATE; METHYLSUCCINATE;

D O I：

10.1002/zaac.19956211021

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A general procedure to synthesize tetramethylammonium salts is presented. Several tetramethylammonium salts were prepared in a crystalline state by solvent-free reaction of trimethylamine and different methyl compounds at mild conditions: [N(CH3)(4)](2)[C2O4] (cubic; a=1114.8(3)pm), [N(CH3)(4)][CO3CH3] (P2(1)/n; a=813.64(3), b=953.36(3), c=1131.3(4)pm, beta = 90.03(1)degrees), [N(CH3)(4)][NO2] (Pmmn; a=821.2(4), b=746.5(3), c=551.5(2)pm), [N(CH3)(4)][CO2H] (Pmmn; a=792.8(7), b=791.7(3), c=563.3(4)pm) and [N(CH3)(?)4] [O2C(CH2),CO2CH3] (P2(1); a=731.1(2), b=826.4(3), c=1025.2(3)pm, beta=110.1(1)degrees). The tetramethylammonium salts were characterized by IR-spectroscopy and X-ray diffraction. The crystal structures of the methylcarbonate and the nitrite are described.

引用

下载

页码：1735 / 1740

页数：6

共 50 条

[1] A STUDY OF SOME TETRAMETHYLAMMONIUM METAL COMPLEXES [(CH3)4N]2CO(NCO),[(CH3)4N]2CO(NCS), [(CH3)4N]2 CO(NCSE), [(CH3)4N]2 ZN(NCO), [(CH3)4N]2 ZN(NCS),?CH3)4N!2 ZN(NCSE)
KERGOAT, R
GUERCHAIS, JE
GENET, F
BULLETIN DE LA SOCIETE FRANCAISE MINERALOGIE ET DE CRISTALLOGRAPHIE, 1970, 93 (02): : 166 - +
[2] INVESTIGATION OF THE EQUILIBRIA OF THE REACTION - CH3(CH2)4OH+(CH3)2C-CH2=CH3(CH2)4OC(CH3)3
ROZHNOV, AM
BARKOV, VI
SHARONOV, KG
TSVETKOV, VS
JOURNAL OF CHEMICAL THERMODYNAMICS, 1990, 22 (04): : 327 - 333
[3] INDICATIONS OF COUPLING CONSTANTS 4IHH IN (CH3)4C (CH3)2O (CH3)2CO AND (CH3)2SO
DREESKAMP, H
ZEITSCHRIFT FUR PHYSIKALISCHE CHEMIE-FRANKFURT, 1968, 59 (5-6): : 321 - +
[4] Structures of Pt2(CH3)4(S(CH3)2)2 and [PtPh2(S(CH3)2)]n (n=2, 3)
Song, DT
Wang, SN
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2002, 648 (1-2) : 302 - 305
[5] The thermoelastic properties of [N(CH3)4]2ZnBr4 and [N(CH3)4]2MnBr4
López-Echarri, A
Ruiz-Larrea, I
Fraile-Rodríguez, A
PHASE TRANSITIONS, 2000, 71 (02) : 101 - 111
[6] The reactions of (CH3)4N+I-, (CH3)4N+ICl2-, (CH3)4N+ICl4- and (CH3)4N+Cl- with trifluoromethylhypochlorite CF3OCl
Minkwitz, Rolf
Bröchler, Raimund
Zeitschrift fur Naturforschung - Section B Journal of Chemical Sciences, 1997, 52 (03): : 401 - 404
[7] The reactions of (CH3)(4)N+I-, (CH3)(4)N+ICl2-, (CH3)(4)N+ICl4- and (CH3)(4)N+Cl- with trifluoromethylhypochlorite CF3OCl
Minkwitz, R
Brochler, R
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1997, 52 (03): : 401 - 404
[8] THE MECHANISM OF PROPENE ELIMINATION FROM THE IMMONIUM IONS CH2=N+(CH3)CH(CH3)2 AND CH2=N+(CH3)CH2CH2CH3
BOWEN, RD
COLBURN, AW
DERRICK, PJ
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1993, (03): : 285 - 287
[9] SYNTHESIS AND CHARACTERIZATION OF THE COMPLEXES OF MO(V) AND MO(VI) WITH THE LIGANDS "HSCH2CH2N(CH3)(CH2)NN(CH3)CH2CH2SH, N= 2,3 - CRYSTAL-STRUCTURE OF H2[MO2O4(SCH2CH2N(CH3)(CH2)3N(CH3)CH2CH2S)2]
KIM, N
KIM, S
VELLA, PA
ZUBIETA, J
INORGANIC & NUCLEAR CHEMISTRY LETTERS, 1978, 14 (12): : 457 - 464
[10] UNIMOLECULAR REACTIONS OF ISOLATED ORGANIC IONS - REACTIONS OF THE IMMONIUM IONS CH2=N+(CH3)CH(CH3)2, CH2=N+(CH3)CH2CH2CH3 AND CH2=N+(CH2CH2CH3)2
BOWEN, RD
COLBURN, AW
DERRICK, PJ
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1993, (12): : 2363 - 2372

← 1 2 3 4 5 →