THE CRYSTAL-STRUCTURE OF THE ORGANOSILICON P-TOLUENESULFONATE (ME3SI)3CSIPH(H)(OSO2C6H4ME-P)

被引：2
|
作者：
ALJUAID, SS [1 ]
ALNASR, AAK [1 ]
EABORN, C [1 ]
HITCHCOCK, PB [1 ]
机构：
[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 455卷 / 1-2期
关键词：
D O I：
10.1016/0022-328X(93)80380-T
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A single crystal X-ray diffraction study of the title compound has shown that the geometry within the OSO2C6H4Me-p group is very similar to that in organic tosylates, but the Si-O-S angle (128.0(5)-degrees) is significantly larger than the corresponding C-O-S angle (ca. 118-degrees) in the latter species.
引用
收藏
页码：57 / 60
页数：4
相关论文
共 50 条
  • [1] CRYSTAL-STRUCTURE OF THE CROWDED SILANOL (ME3SI)3CSIPH2OH
    ALMANSOUR, AI
    ALJUAID, SS
    EABORN, C
    HITCHCOCK, PB
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1994, 480 (1-2) : 139 - 143
  • [2] Synthesis and reactions of highly sterically hindered organosilicon compounds of the type (Me3Si)3CSi(C6H4-OMe-p)MeX and (Me3Si)3CSi(C6H4-Me-p)MeX
    Safa, KD
    Bolourtchian, M
    Asadi, MG
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1999, 149 : 229 - 236
  • [3] REACTIONS AT HIGHLY STERICALLY HINDERED ORGANOSILICON CENTERS - CHEMISTRY OF (ME3SI)3CSIPHHI, (ME3SI)3CSIPH(OME)I, AND RELATED SPECIES
    AIUBE, ZH
    EABORN, C
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 421 (2-3) : 159 - 169
  • [4] INVESTIGATIONS CONCERNING THE REACTIVITY OF THE HIGHER SILYLPHOSPHANES (ME3SI)4P2, [(ME3SI)2P]2PH [(ME3SI)2P]2P-SIME3, AND (ME3SI)3P7
    FRITZ, G
    HARER, J
    SCHEIDER, KH
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1982, 487 (04): : 44 - 58
  • [5] Synthesis and characterisation of cobalt and nickel compounds with phosphinothiol ligands.: Crystal and molecular structures of [CO{2-(Ph2P)-6-(Me3Si) C6H3S)}3], [Ni{2-(Ph2P)-6-(Me3Si)C6H3S)}2] and [Co{2-(Ph2PO)-6-(Me3Si)C6H3S}2]
    Pérez-Lourido, P
    Romero, J
    García-Vázquez, JA
    Sousa, A
    Zubieta, J
    Maresca, K
    POLYHEDRON, 1998, 17 (25-26) : 4457 - 4464
  • [6] Preparation and structural characterisation of the cation-π complexes [{(Me3Si)2NK} • (tBu-C6H5)]2 and [{(Me3Si)2NK} • (Me3-C6H3)]2
    Randazzo, John B.
    Morris, J. Jacob
    Henderson, Kenneth W.
    MAIN GROUP CHEMISTRY, 2006, 5 (03) : 215 - 220
  • [7] Synthesis and reactions of highly sterically hindered organosilicon compounds of the type (Me3Si)3CSi(C6H4OMe-p)2X
    Safa, KD
    Asadi, A
    Sargordan, M
    JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1997, 545 : 61 - 65
  • [8] CRYSTAL-STRUCTURE OF N,N'-BIS(TRIMETHYLSILYL)-IMIDAZOLIUMIODIDE [(ME3SI)2(C3H3N2)]+I-
    HENSEN, K
    MULLER, T
    PICKEL, P
    ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1988, 564 (09): : 101 - 103
  • [9] Crystal structure of carbohydrazidium(1+) p-toluenesulfonate, (NH2NHCONHNH3)[CH3C6H4SO3]
    Yang, L.
    Yu, W.
    Wu, T.
    Zhang, T. -L.
    Zhang, J. -G.
    Guo, J. -Y.
    Wu, R. -F.
    Ren, F-J.
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE-NEW CRYSTAL STRUCTURES, 2006, 221 (03): : 281 - 282
  • [10] SYNTHESIS, REACTIVITY AND CRYSTAL-STRUCTURE OF [RH(C6H5ME)(P(OPH)3)2]CLO4
    USON, R
    LAHUERTA, P
    REYES, J
    ORO, LA
    FOCESFOCES, C
    CANO, FH
    GARCIABLANCO, S
    INORGANICA CHIMICA ACTA-ARTICLES, 1980, 42 (01): : 75 - 84
12345