THE CRYSTAL-STRUCTURE OF THE ORGANOSILICON P-TOLUENESULFONATE (ME3SI)3CSIPH(H)(OSO2C6H4ME-P)

被引：2
|
作者：
ALJUAID, SS [1 ]
ALNASR, AAK [1 ]
EABORN, C [1 ]
HITCHCOCK, PB [1 ]
机构：
[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 455卷 / 1-2期
关键词：
D O I：
10.1016/0022-328X(93)80380-T
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A single crystal X-ray diffraction study of the title compound has shown that the geometry within the OSO2C6H4Me-p group is very similar to that in organic tosylates, but the Si-O-S angle (128.0(5)-degrees) is significantly larger than the corresponding C-O-S angle (ca. 118-degrees) in the latter species.
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页码：57 / 60
页数：4
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