THE CRYSTAL-STRUCTURE OF THE ORGANOSILICON P-TOLUENESULFONATE (ME3SI)3CSIPH(H)(OSO2C6H4ME-P)

被引：2

作者：

ALJUAID, SS ^{[1
]}

ALNASR, AAK ^{[1
]}

EABORN, C ^{[1
]}

HITCHCOCK, PB ^{[1
]}

机构：

[1] UNIV SUSSEX,SCH CHEM & MOLEC SCI,BRIGHTON BN1 9QJ,E SUSSEX,ENGLAND

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1993年 / 455卷 / 1-2期

关键词：

D O I：

10.1016/0022-328X(93)80380-T

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A single crystal X-ray diffraction study of the title compound has shown that the geometry within the OSO2C6H4Me-p group is very similar to that in organic tosylates, but the Si-O-S angle (128.0(5)-degrees) is significantly larger than the corresponding C-O-S angle (ca. 118-degrees) in the latter species.

引用

页码：57 / 60

页数：4

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