(2,2 '-Bipyrimidine-kappa N-2(1),N-1 ')bis(thiocyanato-kappa N)platinum(II)

被引：2
|
作者：
Ha, Kwang [1 ]
机构：
[1] Chonnam Natl Univ, Sch Appl Chem Engn, Res Inst Catalysis, Gwangju 500757, South Korea
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
基金：
新加坡国家研究基金会;
关键词：
D O I：
10.1107/S1600536812017552
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title complex, [Pt(NCS)(2)(C8H6N4)], the Pt-II ion is four-coordinated in a distorted square-planar environment defined by two pyrimidine N atoms derived from a chelating 2,2'-bipyrimidine (bpym) ligand and two mutually cis N atoms from two SCN- anions. The thiocyanate ligands are almost linear, displaying N-C-S bond angles of 178.6 (11) and 173.7 (11)degrees, and the N atoms are slightly bent coordinated to the Pt atom with Pt-N-C bond angles of 172.7 (9) and 160.4 (10)degrees. In the crystal, molecules are held together by C-H center dot center dot center dot S hydrogen bonds. Intramolecular C-H center dot center dot center dot N hydrogen bonds are also observed
引用
收藏
页码：M676 / +
页数：7
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