Bis(thiocyanato-kappa N)[tris(pyridin-2-yl-methyl)amine-kappa N-4]iron(II)

被引：1
|
作者：
Dai, Jing-Wei [1 ]
Li, Zhao-Yang [2 ]
Sato, Osamu [1 ]
机构：
[1] Kyushu Univ, Inst Mat Chem & Engn, 6 1 Kasuga koen, Kasuga, Fukuoka 8168580, Japan
[2] Tohoku Univ, Grad Sch Sci, Dept Chem, Aoba Ku, Sendai, Miyagi 9808578, Japan
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2014年 / 70卷
关键词：
data-to-parameter ratio = 15.7; mean σ(C-C) = 0.009 Å; R factor = 0.069; single-crystal X-ray study; T = 123 K; wR factor = 0.203;
D O I：
10.1107/S1600536813034818
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title complex, [Fe(NCS)(2)(C18H18N4)], the Fe II cation is chelated by a tris(2-pyridylmethyl) amine ligand and coordinated by two thiocyanate anions in a distorted N-6 octahedral geometry. In the crystal, weak C-H center dot center dot center dot S hydrogen bonds and pi-pi stacking interactions between parallel pyridine rings of adjacent molecules [centroid-centroid distance = 3.653 (3) angstrom] link the molecules into a two-dimensional supramolecular architecture. The structure contains voids of 124 (9) angstrom 3, which are free of solvent molecules.
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收藏
页码：M35 / +
页数：9
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