[(4-Methylbenzyl)bis(pyridin-2-ylmethyl)amine-kappa N-3,N ',N '']bis(thiocyanato-kappa S)-copper(II) dichloromethane hemisolvate

被引：1
|
作者：
Qi, Yan [1 ]
Li, Yang [1 ]
Ma, Zheng-Ping [1 ]
Chen, Qiu-Yun [1 ]
机构：
[1] Jiangsu Univ, Sch Chem & Chem Engn, Zhenjiang 212013, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷
关键词：
D O I：
10.1107/S1600536812011476
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Cu(NCS)(2)(C20H21N3)]center dot 0.5CH(2)Cl(2), crystallized with two independent complex molecules ( A and B) in the asymmetric unit, accompanied by one dichloromethane solvent molecule. Each Cu-II atom has a square-pyramidal geometry, being coordinated by five N atoms, three from the (4-methylbenzyl)bis(pyridin-2-ylmethyl) amine ligand and two from the thiocyanate ligands. In the crystal, the B molecules are linked via C-H center dot center dot center dot S interactions, forming chains propagating along [100].
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页码：M468 / +
页数：13
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