[mu-1,2,3,4-Tetrakis(pyridin-4-yl)butane kappa(2) N-1 :N-4]bis[trimethyl(thiocyanato-kappa N)tin(IV)]

被引：2

作者：

Najafi, Ezzatollah ^{[1
]}

Amini, Mostafa M. ^{[1
]}

Ng, Seik Weng ^{[2
,3
]}

机构：

[1] Shahid Beheshti Univ, Dept Chem, Tehran 1983963113, Iran

[2] Univ Malaya, Dept Chem, Kuala Lumpur 50603, Malaysia

[3] King Abdulaziz Univ, Fac Sci, Chem Dept, Jeddah, Saudi Arabia

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2012年 / 68卷

关键词：

D O I：

10.1107/S160053681204737X

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title compound, [Sn-2(CH3)(6)(NCS)(2)(C24H22N4)], the 1,2,3,4-tetrakis(pyridin-4-yl) butane ligand uses the pyridine N atoms at the ends of the butyl chain to coordinate to two trimethylthiocyanatotin(IV) units, forming a dinuclear structure. The Sn IV atom in the molecule shows a distorted transtrigonal-bipyramidal coordination with the methyl groups in equatorial positions. The molecule lies on a center of inversion, with the mid-point of the butyl chain coinciding with this symmetry element. In the crystal, weak C-H center dot center dot center dot interactions occur between pyridine rings of adjacent molecules.

引用

页码：M1550 / +

页数：7

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