SYNTHESIS OF BIS(N-METHYLIMIDAZOL-2-YL)KETONE (BIK) AND CRYSTAL-STRUCTURE OF [ZN(BIK)(2)](CLO4)(2)

被引：21
|
作者：
CHEN, XM [1 ]
XU, ZT [1 ]
MAK, TCW [1 ]
机构：
[1] CHINESE UNIV HONG KONG,DEPT CHEM,SHA TIN,HONG KONG
来源：
POLYHEDRON | 1995年 / 14卷 / 02期
关键词：
D O I：
10.1016/0277-5387(94)00340-K
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel polyimidazole ligand bis(N-methylimidazol-2-yl)ketone (BIK) has been synthesized and its first metal complex [Zn(BIK)(2)](ClO4)(2) has been structurally established by X-ray crystallography. The zinc atom is coordinated by two chelating BIK ligands in a distorted tetrahedral N-4 environment with Zn-N bonds at 1.997(8) Angstrom and N-Zn-N bond angles at 93.5(5)-137.3(5)degrees.
引用
收藏
页码：319 / 322
页数：4
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