SYNTHESIS OF BIS(N-METHYLIMIDAZOL-2-YL)KETONE (BIK) AND CRYSTAL-STRUCTURE OF [ZN(BIK)(2)](CLO4)(2)

被引：21
|
作者：
CHEN, XM [1 ]
XU, ZT [1 ]
MAK, TCW [1 ]
机构：
[1] CHINESE UNIV HONG KONG,DEPT CHEM,SHA TIN,HONG KONG
来源：
POLYHEDRON | 1995年 / 14卷 / 02期
关键词：
D O I：
10.1016/0277-5387(94)00340-K
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A novel polyimidazole ligand bis(N-methylimidazol-2-yl)ketone (BIK) has been synthesized and its first metal complex [Zn(BIK)(2)](ClO4)(2) has been structurally established by X-ray crystallography. The zinc atom is coordinated by two chelating BIK ligands in a distorted tetrahedral N-4 environment with Zn-N bonds at 1.997(8) Angstrom and N-Zn-N bond angles at 93.5(5)-137.3(5)degrees.
引用
收藏
页码：319 / 322
页数：4
相关论文
共 50 条
  • [31] Synthesis and crystal structure of [UO2(OH)(CO(NH 2)2)3]2(ClO4)2
    Serezhkina L.B.
    Peresypkina E.V.
    Virovets A.V.
    Klynin E.S.
    Serezhkin V.N.
    Radiochemistry, 2011, 53 (5) : 457 - 461
  • [32] CRYSTAL-STRUCTURE OF TETRAKIS(2-METHYLPYRAZINE)COPPER(II) PERCHLORATE, [CU(2-MEPZ)4](CLO4)2
    MAEKAWA, M
    KITAGAWA, S
    TANIMURA, T
    MUNAKATA, M
    YONEZAWA, T
    ANALYTICAL SCIENCES, 1992, 8 (06) : 899 - 900
  • [33] Synthesis and Crystal Structure of [Cu(BDBPH)(ClO4)2] (BDBPH = Butane-2,3-dione bis(2′-pyridylhydrazone)
    Bhargab Guhathakurta
    Chiranjan Biswas
    Jnan Prakash Naskar
    Liping Lu
    Miaoli Zhu
    Journal of Chemical Crystallography, 2011, 41 : 1694 - 1699
  • [34] Synthesis and Crystal Structure of [Cu(BDBPH)(ClO4)2] (BDBPH = Butane-2,3-dione bis(2'-pyridylhydrazone)
    Guhathakurta, Bhargab
    Biswas, Chiranjan
    Naskar, Jnan Prakash
    Lu, Liping
    Zhu, Miaoli
    JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2011, 41 (11) : 1694 - 1699
  • [35] A STRONGLY CHELATING BIDENTATE CLO4 - NEW SYNTHESIS ROUTE AND CRYSTAL-STRUCTURE DETERMINATION OF TI(CLO4)4
    FOURATI, M
    CHAABOUNI, M
    BELIN, CH
    CHARBONNEL, M
    PASCAL, JL
    POTIER, J
    INORGANIC CHEMISTRY, 1986, 25 (09) : 1386 - 1390
  • [36] CRYSTAL-STRUCTURE OF AN INFINITE STAIR-TYPE CHAIN COMPOUND [(CU2(TC)2(CLO4)2)N] (TC = THIOCHROME)
    KITAGAWA, S
    MATSUYAMA, S
    MUNAKATA, M
    OSAWA, N
    MASUDA, H
    JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1991, (07): : 1717 - 1720
  • [37] SYNTHESIS, CHARACTERIZATION, AND X-RAY CRYSTAL-STRUCTURE OF [RU(NO2)(PME3)2(TRPY)](CLO4)
    LEISING, RA
    KUBOW, SA
    CHURCHILL, MR
    BUTTREY, LA
    ZILLER, JW
    TAKEUCHI, KJ
    INORGANIC CHEMISTRY, 1990, 29 (07) : 1306 - 1312
  • [38] CRYSTAL-STRUCTURE OF SILVER PERCHLORATE MONOHYDRATE, AG(CLO4)(H2O)
    WARTCHOW, R
    LUDWIG, W
    ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1995, 210 (11): : 879 - 879
  • [39] A DINUCLEAR ZINC CARBOXYLATE COMPLEX OF BIOLOGICAL RELEVANCE - CRYSTAL-STRUCTURE OF [ZN-2(BPY)(2)(MECO(2))(3)]CLO4 (BPY=2,2'-BIPYRIDINE)
    CHEN, XM
    TONG, YX
    MAK, TCW
    INORGANIC CHEMISTRY, 1994, 33 (20) : 4586 - 4588
  • [40] Synthesis, Crystal Structure, and Properties of an Energetic Compound [Zn(1,5-diaminotetrazole)6](ClO4)2
    Shang Jing
    Zhang Jianguo
    Cui Yan
    Zhang Tonglai
    Shu Yuanjie
    Yang Li
    ACTA CHIMICA SINICA, 2010, 68 (03) : 233 - 238
12345