Preparation and crystal structure of [Ag(TO)2]ClO4•H2O

被引：0

作者：

Zhang, JG ^{[1
]}

Zhang, TL

Lu, Z

Yu, KB

机构：

[1] Beijing Inst Technol, Dept Mechanoelect Engn, Beijing 100081, Peoples R China

[2] Chinese Acad Sci, Chengdu Branch, Ctr Anal & Measurement, Chengdu 610041, Peoples R China

来源：

ACTA CHIMICA SINICA | 1999年 / 57卷 / 11期

关键词：

preparation; 1,2,4-triazol-5-one(TO); silver complex; crystal structure;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Ag(TO)(2)]ClO4. H2O was prepared by mixing the aqueous solution of 1,2,4 - triazol - 5 - one(TO) and silver perchlorate, It was characterized by X - ray diffraction, TG - DTG, and IR measurement. The crystalistriclinic, space group P (1) over bar with a = 0.533(1)nm, b = 0.938(1)nm, c = 1.220(1)nm; alpha = 88.02(1)degrees, beta = 79.50(1)degrees, gamma = 82.86(1)degrees; V = 0.5953(8)nm(3), Z = 2, R is 0.0281. The silver atom has a slightly bent linear coordination geometry with two nitrogen atoms.

引用

页码：1233 / 1238

页数：6