KINETICS OF THE ESTERIFICATION OF PALMITIC ACID WITH ISOBUTYL ALCOHOL

被引：29
|
作者：
GOTO, S
TAGAWA, T
YUSOFF, A
机构：
[1] Department of Chemical Engineering, Nagoya University, Nagoya, 464-01, Chikusa
来源：
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS | 1991年 / 23卷 / 01期
关键词：
D O I：
10.1002/kin.550230103
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Kinetics of the sulfuric acid catalyzed esterification of palmitic acid with isobutyl alcohol has been studied and reviewed critically. A theoretical rate equation is derived by the following reaction mechanism: (1) The reaction of sulfuric acid and isobutyl alcohol produces isobutyl sulfuric acid which acts as a catalyst; (2) Palmitic acid is protonated by the catalyst to form the reaction intermediate; and (3) The esterification proceeds reversibily. The experimental results are consistent with this rate equation.
引用
收藏
页码：17 / 26
页数：10
相关论文
共 50 条
  • [11] ESTERIFICATION OF PALMITIC ACID BY SWINE AORTIC HOMOGENATES
    HUANG, WY
    KUMMEROW, FA
    FEDERATION PROCEEDINGS, 1978, 37 (03) : 835 - 835
  • [12] ESTERIFICATION OF PALMITIC ACID IN SWINE AORTIC HOMOGENATES
    HUANG, WY
    KUMEROW, FA
    LIPIDS, 1978, 13 (12) : 873 - 877
  • [13] Kinetics of the esterification of crotonic acid with octyl, decyl, or dodecyl alcohol
    Kulawska, M
    Grzesik, M
    Skrzypek, J
    CHEMICAL PAPERS, 2003, 57 (06): : 424 - 426
  • [14] Kinetics of esterification of acetic acid with propyl alcohol by heterogeneous catalysis
    Bart, HJ
    Kaltenbrunner, W
    Landschutzer, H
    INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1996, 28 (09) : 649 - 656
  • [15] KINETICS OF ESTERIFICATION OF METHACRYLIC-ACID WITH METHYL-ALCOHOL
    CHUBAROV, GA
    DANOV, SM
    EFREMOV, RV
    MINCHUK, FF
    JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1975, 48 (10): : 2393 - 2395
  • [16] KINETICS OF ESTERIFICATION OF ACRYLIC-ACID WITH METHYL-ALCOHOL
    CHUBAROV, GA
    DANOV, SM
    MINCHUK, FF
    BROVKINA, GV
    JOURNAL OF APPLIED CHEMISTRY OF THE USSR, 1976, 49 (12): : 2731 - 2734
  • [17] ESTERIFICATION OF PALMITIC ACID IN SWINE AORTIC MICROSOMES
    HUANG, WY
    KUMMEROW, FA
    BIOCHEMICAL MEDICINE, 1978, 20 (03): : 371 - 377
  • [18] Esterification kinetics of acrylic acid with higher aliphatic alcohol.
    Grzesik, M
    Skrzypek, J
    Witczak, M
    PRZEMYSL CHEMICZNY, 2000, 79 (08): : 271 - +
  • [19] ACOUSTIC SPECTROSCOPY AS A METHOD FOR STUDYING ACTIVE COMPLEX OF ACETIC-ACID ESTERIFICATION BY ISOBUTYL ALCOHOL
    ZINOVEV, OI
    SHAKHPARONOV, MI
    PULATOVA, LF
    PARPIEV, A
    ARTYKOV, A
    ZHURNAL FIZICHESKOI KHIMII, 1978, 52 (07): : 1610 - 1613
  • [20] Liquid Phase Esterification of Acrylic Acid with Isobutyl Alcohol Catalyzed by Different Cation Exchange Resins
    Karakus, Simge
    Sert, Emine
    Buluklu, Asli Deniz
    Atalay, Ferhan Sami
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2014, 53 (11) : 4192 - 4198
12345